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環己烷甲酸甲酯

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環己烷甲酸甲酯
識別
CAS號 4630-82-4  checkY
SMILES
 
  • O=C(OC)C1CCCCC1
性質
化學式 C8H14O2
摩爾質量 142.2 g·mol−1
外觀 液體
沸點 180 °C[1]
相關物質
相關化學品 3,4-環氧環己烷甲酸甲酯
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

環己烷甲酸甲酯是一種有機化合物,化學式為C8H14O2。它可由環己烷甲酸甲醇硫酸存在下回流反應製得。[2]

反應

[編輯]

環己烷甲酸甲酯可以被紅鋁還原為環己烷甲醛維基數據所列Q72459569[3]

它和正辛醇三氟甲磺酸五氟苯銨催化下於甲苯中反應,可以得到環己烷甲酸辛酯。[4]

參考文獻

[編輯]
  1. ^ Kirillov, N.F., Nikiforova, E.A., Vasyanin, A.N. et al. Synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones by reformatsky reaction. Russ J Org Chem 51, 513–517 (2015). doi:10.1134/S1070428015040089
  2. ^ José Maurício dos Santos Filho, Marcos Venícius Batista de Souza Castro. Synthesis, structural characterization, and antimicrobial activity of novel ferrocene-N-acyl hydrazones designed by means of molecular simplification strategy Celebrating the 100th anniversary of the birth of Professor Paulo Freire. Journal of Organometallic Chemistry. 2022. 979. 122488. doi:10.1016/j.jorganchem.2022.122488
  3. ^ Malek, Jaroslav. Reductions by metal alkoxyaluminum hydrides. Part II. Carboxylic acids and derivatives, nitrogen compounds, and sulfur compounds. Organic Reactions, 2004. 36. doi:10.1002/0471264180.or036.03.
  4. ^ Funatomi, Takashi; Wakasugi, Kazunori; Misaki, Tomonori; Tanabe, Yoo. Pentafluorophenylammonium triflate (PFPAT): An efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation. Green Chemistry, 2006. 8 (12). 1022-1027. doi:10.1039/b609181b.