羽扇豆異黃酮
外觀
Luteone | |
---|---|
IUPAC名 2′,4′,5,7-Tetrahydroxy-6-(3-methylbut-2-en-1-yl)isoflavone | |
系統名 3-(2,4-Dihydroxyphenyl)-5,7-dihydroxy-6-(3-methylbut-2-en-1-yl)-4H-1-benzopyran-4-one | |
識別 | |
CAS號 | 41743-56-0 |
PubChem | 5281797 |
ChemSpider | 4445109 |
SMILES |
|
InChI |
|
InChIKey | MMPVAPMCVABQPS-UHFFFAOYSA-N |
3DMet | B03983 |
ChEBI | 27917 |
KEGG | C10498 |
性質 | |
化學式 | C20H18O6 |
摩爾質量 | 354.35 g·mol−1 |
外觀 | 淺黃色柱狀晶體[1] |
熔點 | 223—225 °C(496—498 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
羽扇豆異黃酮是一種異黃酮類有機化合物,化學式為C20H18O6。它存在於毒豆[2]和狹葉羽扇豆[3]中。它可人工合成得到。[4]
在吡啶存在下,它在110 °C和乙酸酐反應,可以得到羽扇豆異黃酮-2',4',5,7-四乙酸酯。[1]
參考文獻
[編輯]- ^ 1.0 1.1 1.2 Masao Tsukayama, Hironari Wada, Yasuhiko Kawamura, Kazuyo Yamashita, Masaki Nishiuchi. Regioselective Synthesis of 6-Alkyl- and 6-Prenylpolyhydroxyisoflavones and 6-Alkylcoumaronochromone Derivatives. Chemical & Pharmaceutical Bulletin (2004), 52(11), 1285-1289. doi:10.1248/cpb.52.1285.
- ^ Sato H.; Tahara S.; Ingham J. L.; Dziedzic S. Z. Isoflavones from pods of Laburnum anagyroides. Phytochemistry. 1995, 39 (3): 673–676. doi:10.1016/0031-9422(95)00029-7.
- ^ Xiaomeng Liang; Jan H. Christensen; Thomas D. Bucheli; Nikoline Juul Nielsen. Source-Supported Suspect Screening (4S) of Phytotoxins in Terrestrial and Aquatic Environments: A Field Study of Lupinus angustifolius L. (Blue Lupin). Environ. Sci. Technol. 2023, 57, 6, 2333–2340. doi:10.1021/acs.est.2c05387.
- ^ Tsukayama M.; Wada H.; Kishida M.; Nishiuchi M.; Kawamura Y. Regioselective Synthesis of Prenylisoflavones. Syntheses of Luteone and Luteone Hydrate. Chem Lett. 2000, 29 (12): 1362–1363. doi:10.1246/cl.2000.1362.