1,5-雙(二苯基膦基)戊烷
外觀
1,5-雙(二苯基膦基)戊烷 | |
---|---|
![]() | |
英文名 | 1,5-Bis(diphenylphosphino)pentane |
別名 | DPPP |
識別 | |
CAS號 | 27721-02-4 ![]() |
PubChem | 2733414 |
ChemSpider | 2015213 |
SMILES |
|
性質 | |
化學式 | C29H30P2 |
摩爾質量 | 440.5 g·mol−1 |
外觀 | 白色無定形粉末 |
熔點 | 41—44 °C(314—317 K)[1] |
危險性 | |
GHS危險性符號![]() | |
GHS提示詞 | 警告 |
H-術語 | H315, H319, H335 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1,5-雙(二苯基膦基)戊烷是一種有機磷化合物,化學式為C29H30P2。它可由1,5-二溴戊烷和二苯基膦基鋰反應,[2]或和二苯基膦在氫氧化銫存在下反應製得。[3]它可以被二氟化氙氧化為1,5-雙(二苯基二氟磷基)戊烷。[4]它和碘化亞銅反應,得到雙核配合物[CuIPh2P(CH2)5PPh2]2。[5]
參考文獻
[編輯]- ^ Shatunov, V.V.; Korlyukov, A.A.; Lebedev, A.V.; Sheludyakov, V.D.; Kozyrkin, B.I.; Orlov, V.Yu. The synthesis and deep purification of GaEt3. Reversible complexation of adducts MAlk3 (M = Al, Ga, In; Alk = Me, Et) with phenylphosphines. Journal of Organometallic Chemistry (Elsevier BV). 2011, 696 (10): 2238–2251. ISSN 0022-328X. doi:10.1016/j.jorganchem.2010.11.044.
- ^ Chou, Ta Shue; Yuan, Jeh Jing; Tsao, Chung Huang. Ultrasonic acceleration of the reductive cleavage of phosphorus-carbon bonds with lithium metal. A simple preparation of tertiary phosphines. Journal of Chemical Research, Synopses. 1985, (1): 18–19. ISSN 0308-2342..
- ^ Honaker, Matthew T.; Salvatore, Ralph Nicholas. A MILD AND EFFICIENT CsOH-PROMOTED SYNTHESIS OF DITERTIARY PHOSPHINES. Phosphorus, Sulfur, and Silicon and the Related Elements (Informa UK Limited). February 1, 2004, 179 (2): 277–283. ISSN 1042-6507. doi:10.1080/10426500490262261.
- ^ Michael H. Holthausen, Rashi R. Hiranandani, Douglas W. Stephan. Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines. Chemical Science. 2015, 6 (3): 2016–2021 [2022-03-02]. ISSN 2041-6520. PMC 5496503
. PMID 28717457. doi:10.1039/C5SC00051C (英語).
- ^ Zhang, Xiayi; Song, Li; Hong, Mingwei; Shi, Hongsheng; Xu, Kaijie; Lin, Qizhong; Zhao, Yi; Tian, Yuan; Sun, Jiafeng; Shu, Kangying; Chai, Wenxiang. Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations. Polyhedron (Elsevier BV). 2014, 81: 687–694. ISSN 0277-5387. doi:10.1016/j.poly.2014.07.034.