1,7-二溴庚烷

1,7-二溴庚烷
識別
CAS號	4549-31-9
性質
化學式	C7H14Br2
摩爾質量	257.99 g·mol⁻¹
密度	1.5306 g·cm−3（20 °C）
熔點	−41.7 °C（231.5 K）
沸點	263 °C（536 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

1,7-二溴庚烷是一種有機化合物，化學式為C₇H₁₄Br₂。它可由1,7-庚二醇和三溴化磷在乙醚重反應得到，^[4]或和氫溴酸在相轉移催化劑的存在下反應製得。^[5]它具有鹵代烴（溴代烴）的通性，如在碳酸鉀的存在下和4-巰基苯酚反應，得到1,7-二(4-羥基苯硫基)庚烷。^[6]它在丙酮中和碘化鈉反應，可以得到1,7-二碘庚烷。^[7]

參考文獻[編輯]

^ Muller, Adolf; Vanc, Wenzel. Multimembered cyclic compounds. XII. Formation of ω,ω'-oxidoalkanes and ω,ω'-dibromodialkyl ethers from diprimary glycols and hydrogen bromide. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1944, 77B. 669-675. ISSN: 0365-9488.
^ William P. Hall, E. Emmet Reid. A Series of α,ι-Dimercaptans 1. Journal of the American Chemical Society. 1943-08, 65 (8): 1466–1468 [2020-11-28]. ISSN 0002-7863. doi:10.1021/ja01248a008. （原始內容存檔於2020-12-10）（英語）.
^ Gordon G. Cash, Suzanne Hartigan, Jay Tunkel. Normal boiling points of haloalkanes from electrotopological state indices. Toxicological & Environmental Chemistry. 2008-11, 90 (6): 1073–1089 [2020-11-28]. ISSN 0277-2248. doi:10.1080/02772240701862116 （英語）.
^ Ben-Sasson, Shmuel; Gross, Einav. Compounds and uses for the treatment and prevention of diseases and conditions associate with or aggravated by impaired mitophagy. 2019. WO 2019175873 A1.
^ Guoqin Hu, Hua Li, Juan Liu, Jiang Zhu. Preparation of Supported CTAB/MCM-41 and CTAB-Nafion/MCM-41 Mesoporous Molecular Sieve and Their Use in the Brominating Reaction. Journal of the Korean Chemical Society. 2011-08-20, 55 (4): 691–696 [2020-11-28]. ISSN 1017-2548. doi:10.5012/jkcs.2011.55.4.691. （原始內容存檔於2018-06-04）（英語）.
^ Yuki Arakawa, Kenta Komatsu, Satoyoshi Inui, Hideto Tsuji. Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase. Journal of Molecular Structure. 2020-01, 1199: 126913 [2020-11-28]. doi:10.1016/j.molstruc.2019.126913 （英語）.
^ Manuel Petroselli, Venkatachalam Angamuthu, Faiz-Ur Rahman, Xinluo Zhao, Yang Yu, Julius Rebek. Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems. Journal of the American Chemical Society. 2020-02-05, 142 (5): 2396–2403 [2020-11-28]. ISSN 0002-7863. doi:10.1021/jacs.9b11595. （原始內容存檔於2022-04-19）（英語）.

[1] Muller, Adolf; Vanc, Wenzel. Multimembered cyclic compounds. XII. Formation of ω,ω'-oxidoalkanes and ω,ω'-dibromodialkyl ethers from diprimary glycols and hydrogen bromide. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1944, 77B. 669-675. ISSN: 0365-9488.

[2] William P. Hall, E. Emmet Reid. A Series of α,ι-Dimercaptans 1. Journal of the American Chemical Society. 1943-08, 65 (8): 1466–1468 [2020-11-28]. ISSN 0002-7863. doi:10.1021/ja01248a008. （原始內容存檔於2020-12-10）（英語）.

[3] Gordon G. Cash, Suzanne Hartigan, Jay Tunkel. Normal boiling points of haloalkanes from electrotopological state indices. Toxicological & Environmental Chemistry. 2008-11, 90 (6): 1073–1089 [2020-11-28]. ISSN 0277-2248. doi:10.1080/02772240701862116 （英語）.

[4] Ben-Sasson, Shmuel; Gross, Einav. Compounds and uses for the treatment and prevention of diseases and conditions associate with or aggravated by impaired mitophagy. 2019. WO 2019175873 A1.

[5] Guoqin Hu, Hua Li, Juan Liu, Jiang Zhu. Preparation of Supported CTAB/MCM-41 and CTAB-Nafion/MCM-41 Mesoporous Molecular Sieve and Their Use in the Brominating Reaction. Journal of the Korean Chemical Society. 2011-08-20, 55 (4): 691–696 [2020-11-28]. ISSN 1017-2548. doi:10.5012/jkcs.2011.55.4.691. （原始內容存檔於2018-06-04）（英語）.

[6] Yuki Arakawa, Kenta Komatsu, Satoyoshi Inui, Hideto Tsuji. Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase. Journal of Molecular Structure. 2020-01, 1199: 126913 [2020-11-28]. doi:10.1016/j.molstruc.2019.126913 （英語）.

[7] Manuel Petroselli, Venkatachalam Angamuthu, Faiz-Ur Rahman, Xinluo Zhao, Yang Yu, Julius Rebek. Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems. Journal of the American Chemical Society. 2020-02-05, 142 (5): 2396–2403 [2020-11-28]. ISSN 0002-7863. doi:10.1021/jacs.9b11595. （原始內容存檔於2022-04-19）（英語）.

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