1,4,7,10,13,16-六氮雜環十八烷
外觀
1,4,7,10,13,16-六氮雜環十八烷 | |
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別名 | 六環烯 氮雜-18-冠-6 |
識別 | |
CAS號 | 296-35-5 ? |
PubChem | 41779 |
ChemSpider | 38121 |
SMILES |
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性質 | |
化學式 | C12H30N6 |
摩爾質量 | 258.41 g·mol−1 |
外觀 | white solid |
熔點 | 201 °C(474 K) |
危險性 | |
GHS危險性符號![]() | |
GHS提示詞 | 警告 |
H-術語 | H315, H319 |
P-術語 | P264, P280, P302+352, P305+351+338, P321, P332+313, P337+313, P362 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1,4,7,10,13,16-六氮雜環十八烷是一種大環配體,化學式為(CH2CH2NH)6。它是18-冠-6的N6類似物,為白色固體。這種氮雜冠醚在配位化學中是一種六齒配體。[1]
![](http://upload.wikimedia.org/wikipedia/commons/thumb/f/f3/Co%28%28CH2CH2NH%296%29%2B%2B%2B%28BIGNOU01%29.png/220px-Co%28%28CH2CH2NH%296%29%2B%2B%2B%28BIGNOU01%29.png)
它的質子化衍生物通過氫鍵和陰離子連接。[3]
參考文獻
[編輯]- ^ Atkins, T. J.; Richman, J. E.; Oettle, W. F. 1,4,7,10,13,16-Hexaazacyclooctadecane. Org. Syn. 1978, 58: 86. doi:10.15227/orgsyn.058.0086.
- ^ Morooka, M.; Ohba, S.; Toriumi, K. Electron-density distribution in crystals of 1,4,7,10,13,16-hexaazacyclooctadecanecobalt(III) trichloride, meso-[Co(hexaen)]Cl3 at 106 K. Acta Crystallographica Section B Structural Science. 1992, 48 (4): 459–463. doi:10.1107/S0108768192002714.
- ^ Fonari, Marina S.; Ganin, Eduard V.; Gelmboldt, Vladimir O.; Basok, Stepan S.; Luisi, Brian S.; Moulton, Brian. Binding of fluoro-containing anions to hexaazamacrocyclic ligand: Competitive interactions of fluoride and tetrafluoroborate anions with hexaprotonated [18]aneN6. Inorganic Chemistry Communications. 2008, 11 (5): 497–501. doi:10.1016/j.inoche.2008.01.028.