吡啶𬭩苦味酸盐
| 吡啶𬭩苦味酸盐 | |
|---|---|
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| 识别 | |
| CAS号 | 1152-90-5 
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| SMILES |
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| 性质 | |
| 化学式 | C11H8N4O7 |
| 摩尔质量 | 308.2 g·mol−1 |
| 外观 | 黄色晶体[1] |
| 熔点 | 163~164 °C[2] 165.5~167.5 °C[3] |
| 沸点 | 195~200 °C（分解）[4] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
吡啶𬭩苦味酸盐是一种有机化合物，化学式为C11H8N4O7，它可由吡啶和苦味酸在甲醇中以1:1计量比反应制得。[1]五苯基硼唑吡啶配合物和苦味酸反应，也能得到吡啶𬭩苦味酸盐。[5]它和三氯氧磷在苯中回流，可以得到苦基氯；[6]它和二乙氨基三氟化硫反应，可以得到苦基氟。[7]
参考文献
[编辑]- ^ 1.0 1.1 Athmane Meddour, Abdelkader Azizi. Synthesis and spectral investigations of pyridinium picrate. J. Mol. Struct., 2017. 1128: 499-506. doi:10.1016/j.molstruc.2016.07.032
- ^ Sandhu, J., Saini, A., & Kumar, S. (2006). An Efficient and General Method for the Deoxygenation of Organic N-Oxides Using Zn(OTf)2 and Cu(OTf)2 . Synlett, 2006(03), 0395–0398. doi:10.1055/s-2006-926269
- ^ The preparation of some substituted pyridine 1-oxides. J. Chem. Soc., 1956, 2404-2408. doi:10.1039/JR9560002404.
- ^ Syntheses of Morphine-like Structures. I. 9-Hydroxymethyl-2, 5-dimethyl-6, 7-benzomorphan. Chemical and Pharmaceutical Bulletin, 1963. doi:10.1248/cpb.11.986
- ^ Journal of the American Chemical Society. 1986. 108 (3): 379-385. doi:10.1021/ja00263a006.
- ^ Dynamic NMR spectroscopy of three 2,2′-dialkyl/aryl-1-picrylhydrazines in liquid solution. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2010. 381-388. doi:10.1016/j.saa.2009.10.045.
- ^ A new, mild preparation of 2,4,6-trinitrofluorobenzene. Organic Preparations and Procedures International, 1992. doi:10.1080/00304949209356698.