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1,4-二氢吡啶

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1,4-二氢吡啶
Skeletal formula of dihydropyridine
Ball-and-stick model of the dihydropyridine molecule
系统名
1,4-Dihydropyridine[1]
识别
CAS号 3337-17-5  checkY
PubChem 104822
ChemSpider 94619
SMILES
 
  • C1C=CNC=C1
MeSH 1,4-dihydropyridine
性质
化学式 C
5
H
7
N
摩尔质量 81.1158 g mol−1 g·mol⁻¹
密度 0.910±0.06 g·cm−3[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1,4-二氢吡啶(英语:1,4-Dihydropyridine,缩写DHP)是一种不稳定的有机化合物,化学式为C5H7N,其零点振动能为0.1125 Ha[3]。它可由1-三甲基硅基-1,4-二氢吡啶和甲醇反应[4],或吡啶氢化铝锂反应[5]得到,后者会同时产生其它二氢吡啶的异构体。

参考文献

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  1. ^ 1,4-dihydropyridine - Compound Summary. Pubchem Compound. USA: National Center for Biotechnology Information. Identification and Related Records. 27 March 2005 [1 November 2011]. (原始内容存档于2012-10-11). 
  2. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-14]
  3. ^ Lan-Fen Wang, Hong-Yu Zhang, Ling Kong, Zhi-Wei Chen, Jian-Guo Shi. DFT Calculations Indicate that 1,4-Dihydropyridine Is a Promising Lead Antioxidant. Helvetica Chimica Acta. 2004-06, 87 (6): 1515–1521 [2019-11-14]. ISSN 0018-019X. doi:10.1002/hlca.200490138 (英语). 
  4. ^ Newell C. Cook, James E. Lyons. 1,4-Dihydropyridine. Journal of the American Chemical Society. 1965-07, 87 (14): 3283–3284 [2019-11-14]. ISSN 0002-7863. doi:10.1021/ja01092a074 (英语). 
  5. ^ Arthur J. Birch, Edouard A. Karakhanov. Preparation of some N-substituted 1,4-dihydropyridines by metal–ammonia reactions. J. Chem. Soc., Chem. Commun. 1975, (12): 480–481 [2019-11-14]. ISSN 0022-4936. doi:10.1039/C39750000480 (英语). 

参见

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