乙醯丙酮鈥是一種配位化合物，化學式為Ho(C5H7O2)3，或簡寫為Ho(acac)3。它可由金屬鈥[3]或三氫化鈥[1]和乙醯丙酮反應製得，或由氯化鈥和乙醯丙酮銨反應[2]得到。
它以8配位的二水合物Ho(C5H7O2)3(H2O)2存在，結構已表徵。[4]和其它鑭系元素乙醯丙酮配合物一樣，加熱乙醯丙酮鈥的水合物無法得到無水物，只會分解。[5]
參考文獻[編輯]
- ^ 1.0 1.1 1.2 Janice M. Koehler, William G. Bos. A novel synthesis of some anhydrous rare earth acetylacetonates. Inorganic and Nuclear Chemistry Letters. 1967-12, 3 (12): 545–548 [2021-09-20]. doi:10.1016/0020-1650(67)80023-0 （英語）.
- ^ 2.0 2.1 S. K. Zeisler, K. Weber. Szilard-Chalmers effect in holmium complexes. Journal of Radioanalytical and Nuclear Chemistry. 1998-01, 227 (1-2): 105–109 [2021-09-20]. ISSN 0236-5731. doi:10.1007/BF02386438 （英語）.
- ^ J.R. Blackborow, C.R. Eady, E.A.Koerner Von Gustorf, A. Scrivanti, O. Wolfbeis. Chemical syntheses with metal atoms. Journal of Organometallic Chemistry. 1976-03, 108 (3): C32–C34 [2021-09-20]. doi:10.1016/S0022-328X(00)92025-4. （原始內容存檔於2018-06-26） （英語）.
- ^ Kooijman, Huub; Nijsen, Frank; Spek, Anthony L.; Schip, Fred van het. Diaquatris(pentane-2,4-dionato-O,O′)holmium(III) monohydrate and diaquatris(pentane-2,4-dionato-O,O′)holmium(III) 4-hydroxypentan-2-one solvate dihydrate. Acta Crystallographica Section C Crystal Structure Communications. 2000, 56 (2): 156–158. PMID 10777870. doi:10.1107/S0108270199013566
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- ^ Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael. Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters. Nat. Catal. 2020, 3 (2): 154–162. S2CID 209897045. doi:10.1038/s41929-019-0405-5.
拓展閱讀[編輯]
3(H2O)2.svg)
