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2,5-二甲基-1,4-二硫雜-2,5-環己二醇

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2,5-二甲基-1,4-二硫雜-2,5-環己二醇
識別
CAS號 55704-78-4  checkY
性質
化學式 C6H12O2S2
摩爾質量 180.29 g·mol−1
熔點 117-118 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

2,5-二甲基-1,4-二硫雜-2,5-環己二醇是一種有機化合物,化學式為C6H12O2S2。它可由氯丙酮硫氫化鈉為原料反應製得。[2]它在乙腈中和亞苄基丙二腈加熱反應,可以得到二氫-4-羥基-4-甲基-2-苯基-3,3(2H)-噻吩二甲腈。[3]

參考文獻

[編輯]
  1. ^ Thiel, Max; Asinger, Friedrich. Concomitant action of elementary sulfur and gaseous ammonia on ketones. IV. Concomitant action of sulfur and ammonia on acetone. Justus Liebigs Annalen der Chemie, 1957. 610: 17-24. ISSN 0075-4617.
  2. ^ Brown, Michael D.; Gillon, David W.; Meakins, G. Denis; Whitham, Gordon H. A new general synthesis of 2-(N-mono- and N-disubstituted amino)​thiazoles. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985. 8: 1623-1626. ISSN 0300-922X.
  3. ^ Itaru Suzuki, Yuki Sakamoto, Yuta Seo, Yoriko Ninomaru, Kodai Tokuda, Ikuya Shibata. Synthesis of 5-Membered Sulfur Heterocycles via Tin-Catalyzed Annulation of Mercapto Ketones with Activated Alkenes. The Journal of Organic Chemistry. 2020-02-21, 85 (4): 2759–2769 [2022-03-24]. ISSN 0022-3263. doi:10.1021/acs.joc.9b03055.