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肉桂基氯

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肉桂基氯
别名 苯丙烯基氯
识别
CAS号 2687-12-9  checkY
性质
化学式 C9H9Cl
摩尔质量 152.62 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

肉桂基氯是一种有机化合物,化学式为C9H9Cl。它可由肉桂醇氯化亚砜[1]乙酰氯[2]反应制得。它和六甲基二锗Pd2(dba)3催化下反应,得到肉桂基三甲基锗。[3]它和三甲基氰硅烷铜化合物催化下反应,可以得到4-苯基-3-丁烯腈。[4]

参考文献

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  1. ^ Hiroyuki Nakamura, Taikou Usui, Hirokazu Kuroda, Ilhyong Ryu, Hiroshi Matsubara, Shinji Yasuda, Dennis P. Curran. Fluorous Solvent as a New Phase-Screen Medium between Reagents and Reactants in the Bromination and Chlorination of Alcohols. Organic Letters. 2003-04-01, 5 (8): 1167–1169 [2023-03-25]. ISSN 1523-7060. doi:10.1021/ol034060w. (原始内容存档于2023-03-25) (英语). 
  2. ^ Veejendra K Yadav, K Ganesh Babu. Acetyl chloride–ethanol brings about a remarkably efficient conversion of allyl acetates into allyl chlorides. Tetrahedron. 2003-11, 59 (46): 9111–9116 [2023-03-25]. doi:10.1016/j.tet.2003.09.063. (原始内容存档于2018-06-24) (英语). 
  3. ^ Taichi Nakano, Sigeyuki Nöda, Nao-aki A-ihara, Hirohide Yamashita, Takashi Miyamoto, Toshihiko Migita†, Tatsuki Enokido, Masanori Kosugi. HIGH-YIELD FORMATION OF ALLYLIC GERMANES BY Pd2(dba)3-CATALYZED REACTION OF ALLYLIC HALIDES WITH DIGERMANES. Main Group Metal Chemistry. 2001-01, 24 (2) [2023-03-25]. ISSN 2191-0219. doi:10.1515/MGMC.2001.24.2.67. (原始内容存档于2023-03-25). 
  4. ^ Daisuke Munemori, Hiroaki Tsuji, Kenta Uchida, Tomoaki Suzuki, Kazuki Isa, Maki Minakawa, Motoi Kawatsura. Copper-Catalyzed Regioselective Allylic Cyanation of Allylic Compounds with Trimethylsilyl Cyanide. Synthesis. 2014-07-09, 46 (20): 2747–2750 [2023-03-25]. ISSN 0039-7881. doi:10.1055/s-0034-1378322. (原始内容存档于2018-06-02) (英语).