1-萘硒酚
| 1-萘硒酚 | |
|---|---|
| |
| 英文名 | 1-Selenonaphthol 1-Naphthaleneselenol |
| 别名 | α-萘硒酚 |
| 识别 | |
| CAS号 | 16645-11-7 
|
| 性质 | |
| 化学式 | C10H8Se |
| 摩尔质量 | 207.13 g·mol⁻¹ |
| 熔点 | 114 °C（387 K）[1] |
| 沸点 | 165—167 °C（438—440 K）（20 Torr）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
1-萘硒酚是一种有机硒化合物，化学式为C10H7SeH。它可由1-溴萘的格氏试剂和硒反应，再经酸化处理得到。[3]它可以和碘甲烷反应，生成1-甲硒基萘。[4]
相关物质
[编辑]1-萘碲酚是1-萘硒酚的类似物，化学式为C10H7TeH，CAS号735222-00-1，熔点126.5 °C。[1]
参考文献
[编辑]- ^ 1.0 1.1 Lyons, R. E.; Bush, G. C. CONCERNING α-DINAPHTHYL SELENIDE AND TELLURIDE.. Journal of the American Chemical Society. 1908, 30 (5): 831–836. ISSN 0002-7863. doi:10.1021/ja01947a023.
- ^ Taboury, F. Contribution to the Study of Sulphur and Selenium Compounds of the Aromatic Series. Annales de Chimie et de Physique, 1908. 15: 5-66. ISSN: 0365-1444.
- ^ Sun, Jiangtao; Yang, Minghua; Yuan, Fang; Jia, Xuefeng; Yang, Xia; Pan, Yi; Zhu, Chengjian. Catalytic Asymmetric Ring-Opening Reaction ofmeso-Epoxides with Aryl Selenols and Thiols Catalyzed by a Heterobimetallic Gallium-Titanium-Salen Complex. Advanced Synthesis & Catalysis. 2009, 351 (6): 920–930. ISSN 1615-4150. doi:10.1002/adsc.200800767.
- ^ Hayashi, Satoko; Nakanishi, Waro; Furuta, Atsushi; Drabowicz, Jozef; Sasamori, Takahiro; Tokitoh, Norihiro. How does non-covalent Se⋯Se:O interaction stabilize selenoxides at naphthalene 1,8-positions: structural and theoretical investigations. New J. Chem. 2009, 33 (1): 196–206. ISSN 1144-0546. doi:10.1039/B809763A.