五乙酸二锝

五乙酸二锝
识别
CAS号	2411771-86-1
性质
化学式	C10H15O10Tc2
摩尔质量	489.22 g·mol−1
外观	浅紫色晶体
密度	2.071 g·cm−3（100 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五乙酸二锝是一种配位聚合物，化学式为Tc₂(O₂CCH₃)₄(O₂CCH₃)。它可由高锝酸钾和乙酸在60~70 atm的氢气气氛中于200 °C反应得到^[1]，或通过二氧化锝和乙酸、乙酸酐在240~250 °C反应得到。^[2]其分子中的[Tc₂(O₂CCH₃)₄]⁺单元经桥联乙酸根配体连接，形成长链。^[1]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 ^1.3 William M. Kerlin, Frederic Poineau, Kenneth R. Czerwinski, Alfred P. Sattelberger, Paul M. Forster. Solvothermal synthesis and solid-state characterization of metal-metal bonded tetracarboxylatoditechnetium(II,III) polymers. Polyhedron. 2020-04, 180: 114418 [2023-02-24]. doi:10.1016/j.poly.2020.114418 （英语）.
^ М.А. Volkov, А.М. Fedoseev, E.G. Krivoborodov, I.Y. Toropygin, К.E. German, М.S. Grigoriev, V.V. Kuznetsov, N.А. Budantseva, А.P. Novikov, Y.O. Mezhuev. A new method for the synthesis of polynuclear carboxylate complexes of technetium (II, III). Journal of Organometallic Chemistry. 2022-01, 957: 122146 [2023-02-24]. doi:10.1016/j.jorganchem.2021.122146. （原始内容存档于2022-11-11）（英语）.

[Kerlin-1] 1.0 ^1.1 ^1.2 ^1.3 William M. Kerlin, Frederic Poineau, Kenneth R. Czerwinski, Alfred P. Sattelberger, Paul M. Forster. Solvothermal synthesis and solid-state characterization of metal-metal bonded tetracarboxylatoditechnetium(II,III) polymers. Polyhedron. 2020-04, 180: 114418 [2023-02-24]. doi:10.1016/j.poly.2020.114418 （英语）.

[2] М.А. Volkov, А.М. Fedoseev, E.G. Krivoborodov, I.Y. Toropygin, К.E. German, М.S. Grigoriev, V.V. Kuznetsov, N.А. Budantseva, А.P. Novikov, Y.O. Mezhuev. A new method for the synthesis of polynuclear carboxylate complexes of technetium (II, III). Journal of Organometallic Chemistry. 2022-01, 957: 122146 [2023-02-24]. doi:10.1016/j.jorganchem.2021.122146. （原始内容存档于2022-11-11）（英语）.

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