氟氯碘甲烷是一种有机化合物，化学式为CHClFI，是三卤代甲烷的一种，为手性分子[3]。它可由氯二碘甲烷和氟化汞反应得到。[2]在100 mmHg、110 °C加热干燥的(+)-马钱子碱氟氯碘乙酸盐，可以得到(+)-氟氯碘甲烷（ee 63.3%）。[4]
参考文献[编辑]
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- ^ 2.0 2.1 Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X （英语）.
- ^ A. Cuisset, J. R. Aviles Moreno, T. R. Huet, D. Petitprez, J. Demaison, J. Crassous. The Chiral Molecule CHClFI: First Determination of Its Molecular Parameters by Fourier Transform Microwave and Millimeter-Wave Spectroscopies Supplemented by ab Initio Calculations. The Journal of Physical Chemistry A. 2005-06-01, 109 (25): 5708–5716 [2021-11-02]. ISSN 1089-5639. doi:10.1021/jp0443658. （原始内容存档于2021-11-05） （英语）.
- ^ Jeanne Crassous, Zhengjin Jiang, Volker Schurig, Prasad L. Polavarapu. Preparation of (+)-chlorofluoroiodomethane, determination of its enantiomeric excess and of its absolute configuration. Tetrahedron: Asymmetry. 2004-07, 15 (13): 1995–2001 [2021-11-02]. doi:10.1016/j.tetasy.2004.06.006. （原始内容存档于2018-06-15） （英语）.
