氯化三(2,2'-联吡啶)合铁(II)

氯化三(2,2'-联吡啶)合铁(II)
识别
CAS号	14751-83-8
PubChem	203609
ChemSpider	176367
SMILES	C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.[Cl-].[Cl-].[Fe+2];
性质
化学式	C30H24Cl2FeN6
摩尔质量	595.3 g·mol−1
外观	红色固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氯化三(2,2'-联吡啶)合铁(II)是一种配位化合物，化学式为[Fe(C₁₀H₈N₂)₃]Cl₂，可简写为[Fe(bipy)₃]Cl₂，为红色固体。由于primogenic效应，其激发态迟豫太快，相比于氯化三(联吡啶)合钌(II)来说，它难以作为光敏剂（英语：Photosensitizer）有所应用。

它可由2,2'-联吡啶和氯化亚铁在水、乙腈、乙醇或1,2-二氯乙烷中反应制得。^[1]它在升华装置内减压下于80 °C加热，可以得到深蓝色的FeCl₂(bipy)₂。^[2]

参考文献[编辑]

^ Avdeeva, Varvara V.; Vologzhanina, Anna V.; Goeva, Lyudmila V.; Malinina, Elena A.; Kuznetsov, Nikolay T. Boron Cluster Anions [B_nH_n]^2– (n = 10, 12) in Reactions of Iron(II) and Iron(III) Complexation with 2, 2′‐Bipyridyl and 1, 10‐Phenanthroline. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2014-07-09, 640 (11): 2149–2160. ISSN 0044-2313. doi:10.1002/zaac.201400137.
^ Yang, Ping; Chan, Bryan C. K.; Baird, Michael C. Is FeEt₂(2,2‘-dipyridyl)₂ a Ziegler Catalyst for Polymerization of the Polar Monomer Acrylonitrile?. Organometallics (American Chemical Society (ACS)). 2004-04-22, 23 (11): 2752–2761. ISSN 0276-7333. doi:10.1021/om0499613.

[1] Avdeeva, Varvara V.; Vologzhanina, Anna V.; Goeva, Lyudmila V.; Malinina, Elena A.; Kuznetsov, Nikolay T. Boron Cluster Anions [B_nH_n]^2– (n = 10, 12) in Reactions of Iron(II) and Iron(III) Complexation with 2, 2′‐Bipyridyl and 1, 10‐Phenanthroline. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2014-07-09, 640 (11): 2149–2160. ISSN 0044-2313. doi:10.1002/zaac.201400137.

[2] Yang, Ping; Chan, Bryan C. K.; Baird, Michael C. Is FeEt₂(2,2‘-dipyridyl)₂ a Ziegler Catalyst for Polymerization of the Polar Monomer Acrylonitrile?. Organometallics (American Chemical Society (ACS)). 2004-04-22, 23 (11): 2752–2761. ISSN 0276-7333. doi:10.1021/om0499613.

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