4-甲氧基亚苄基丙二腈
| 4-甲氧基亚苄基丙二腈 | |
|---|---|
| |
| 识别 | |
| CAS号 | 2826-26-8 
|
| 性质 | |
| 化学式 | C11H8N2O |
| 摩尔质量 | 184.19 g·mol−1 |
| 熔点 | 115 °C（388 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
4-甲氧基亚苄基丙二腈是一种有机化合物，化学式为C11H8N2O，可由4-甲氧基苯甲醛和丙二腈的Knoevenagel反应制得。[2][3]它和氨硼烷发生加氢反应，得到4-甲氧基苄基丙二腈。[2]它和2-碘丙烷、三乙基铝在过氧化苯甲酰的存在下于乙醚中反应，可以得到2-[1-(4-甲氧基苯基)-2-甲基丙基]丙二腈。[4]
参考文献[编辑]
- ^ Dry Media Reaction Procedure for Synthesis of α,β-Unsaturated Acids, α-Cyanoacrylonitriles and α-Cyanoacrylates via Knoevenagel Condensation Using NaHSO 4 ·SiO 2 Catalyst. Journal of the Korean Chemical Society. 2007-08-20, 51 (4): 346–351 [2021-05-31]. ISSN 1017-2548. doi:10.5012/jkcs.2007.51.4.346. （原始内容存档于2018-06-02） （英语）.
- ^ 2.0 2.1 Jing Li, Martin J. Lear, Yujiro Hayashi. Direct Cyclopropanation of α‐Cyano β‐Aryl Alkanes by Light‐Mediated Single Electron Transfer Between Donor–Acceptor Pairs. Chemistry – A European Journal. 2021-04, 27 (19): 5901–5905 [2021-05-31]. ISSN 0947-6539. doi:10.1002/chem.202100341 （英语）.
- ^ Biwei Yan, Linhong Zuo, Xiaowei Chang, Teng Liu, Manying Cui, Yang Liu, Haiyu Sun, Weipeng Chen, Wusheng Guo. Kinetically Controllable Pd-Catalyzed Decarboxylation Enabled [5 + 2] and [3 + 2] Cycloaddition toward Carbocycles Featuring Quaternary Carbons. Organic Letters. 2021-01-15, 23 (2): 351–357 [2021-05-31]. ISSN 1523-7060. doi:10.1021/acs.orglett.0c03856 （英语）.
- ^ Jing-Yuan Liu, Yoeng-Jiunn Jang, Wen-Wei Lin, Ju-Tsung Liu, Ching-Fa Yao. Triethylaluminum- or Triethylborane-Induced Free Radical Reaction of Alkyl Iodides and α,β-Unsaturated Compounds. The Journal of Organic Chemistry. 2003-05-01, 68 (10): 4030–4038 [2021-05-31]. ISSN 0022-3263. doi:10.1021/jo020681b （英语）.