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9-十八炔

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9-十八炔
识别
CAS号 35365-59-4  checkY
性质
化学式 C18H34
摩尔质量 250.46 g·mol−1
熔点 −0.4 °C[1]
沸点 179 °C(17 mmHg)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

9-十八炔是一种有机化合物,化学式为C18H34,它是十八炔同分异构体之一。它可由1-溴辛烷和乙炔锂及氨基锂反应制得。[1]它可以在液氨中被还原为9-十八烯[2]

它具有抗氧化和抗菌活性[3],存在于香丝草[4]牧豆树种荚[5]中。它在酶处理后的柑橘精油中被检出。[6]

参考文献

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  1. ^ 1.0 1.1 1.2 B. B. Elsner; P. F. M. Paul. The application of lithium alkynyls in the synthesis of long-chain dialkylacetylenes. J. Chem. Soc., 1951, 893-897. doi:10.1039/JR9510000893.
  2. ^ B. B. Elsner; P. F. M. Paul. Synthesis of cis- and trans-octadecenes. Selective catalytic hydrogenation of acetylenes. J. Chem. Soc., 1953, 3156-3160. doi:10.1039/JR9530003156.
  3. ^ A. Vanitha, K. Kalimuthu, V. Chinnadurai, K. M. Jerun Nisha. Phytochemical screening, FTIR and GCMS analysis of aqueous extract of Caralluma bicolor – An endangered plant. Asian Journal of Pharmacy and Pharmacology 2019; 5(6): 1122-1130. doi:10.31024/ajpp.2019.5.6.7
  4. ^ Kodjo Adande, Kodjo Eloh, Oudjaniyobi Simalou, Marie-France Bakaï, Pierluigi Caboni. Chemical Composition of Different Extracts of Conyza bonariensis: Insecticidal and Nematicidal Activities. American Journal of Analytical Chemistry, 2023. 14 (2). doi:10.4236/ajac.2023.142006.
  5. ^ Kumarasamy Dhivyal; et al. Bioprospecting of Prosopis juliflora (Sw.) DC seed pod extract effect on antioxidant and immune system of Spodoptera litura (Lepidoptera: Noctuidae). Physiological and Molecular Plant Pathology, 2018. 101: 45-53. doi:10.1016/j.pmpp.2017.09.003
  6. ^ Kun Zhang, Ying Lin, Zhou-Jian Diao, Wei-Hua Zhang, Sui-Ping Zheng, Shu-Li Liang, Shuang-Yan Han. Enzymatic Process Enhances the Flavour Profile and Increases the Proportion of Esters in Citrus Essential Oils. Chemistry & Biodiversity. 2017. 14 (11): e1700187. doi:10.1002/cbdv.201700187.