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N-甲基己胺

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N-甲基己胺
识别
CAS号 35161-70-7  checkY
性质
化学式 C7H17N
摩尔质量 115.22 g·mol−1
密度 0.761 g·cm−3(20 °C)[1]
沸点 135 °C(408 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

N-甲基己胺是一种有机化合物,化学式为C7H17N。它可由甲胺次氯酸钠和二甲基正己基硼(或三己基硼[3])反应制得。[4]它和亚硝酸钠甲磺酸-氧化铝催化下反应,可以得到N-亚硝基-N-甲基己胺。[5]它和溴化氰反应,可以得到N-氰基-N-甲基己胺。[6]

参考文献

[编辑]
  1. ^ Loffler, Karl. Formation of N-Alkyl Pyrrolidines. Berichte der Deutschen Chemischen Gesellschaft, 1910. 43: 2035-2048. ISSN 0365-9496.
  2. ^ Emmanuel Yankep, Henriette Kapnang, Georges Charles. Alkylaminomethylation d'organomagnesiens. Tetrahedron Letters. 1989-01, 30 (52): 7383–7384 [2022-02-22]. doi:10.1016/S0040-4039(00)70703-9. (原始内容存档于2018-06-08) (英语). 
  3. ^ George W. Kabalka, Zhe Wang. Reaction of trialkylboranes with alkylamines: synthesis of dialkylamines. Organometallics. 1989-04, 8 (4): 1093–1095 [2022-02-22]. ISSN 0276-7333. doi:10.1021/om00106a034. (原始内容存档于2022-02-22) (英语). 
  4. ^ George W. Kabalka, Zhe Wang. Preparation of Isomerically Pure Dialkylamines via the Reaction of Dimethylalkylboranes with Chloroalkylamine. Synthetic Communications. 1990-01, 20 (2): 231–237 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397919008052288 (英语). 
  5. ^ Khodabakhsh Niknam, Mohammad Ali Zolfigol. Alumina–Methanesulfonic Acid (AMA)/NaNO 2 as an Efficient Procedure for the Chemoselectivite N‐Nitrosation of Secondary Amines. Synthetic Communications. 2006-08, 36 (16): 2311–2319 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397910600639927 (英语). 
  6. ^ Toru Hashimoto, Satoshi Ishii, Reiko Yano, Hiroki Miura, Ken Sakata, Ryo Takeuchi. Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Cyanamides. Advanced Synthesis & Catalysis. 2015-12-14, 357 (18): 3901–3916 [2022-02-22]. doi:10.1002/adsc.201500637. (原始内容存档于2022-02-22) (英语).