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氟硼酸鎳

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氟硼酸鎳

識別
CAS號 14708-14-6(無水)  checkY
14322-78-2(六水,配位水)  checkY
15684-36-3(六水,結晶水)  checkY
性質
化學式 Ni(BF4)2
熔點 64 °C(六水)[1]
沸點 205 °C(六水,分解)[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

氟硼酸鎳是一種無機化合物,化學式為Ni(BF4)2,可由鹼式碳酸鎳氟硼酸反應製得。[3]它的六水合物在120 °C長時間加熱,會緩慢分解,[1]這源自於Ni2+催化BF4水解為BF3OH和HF。[4]它和4-氨基-1,2,4-三氮唑(NH2trz)反應,可以得到藍色的[Ni3(NH2trz)6(H2O)6](BF4)6·4H2O。[5]它和[PPN]3[Os(CN)6]反應,可以得到紅橙色的Ni3[Os(CN)6]2·4.04H2O。[6]

參考文獻

[編輯]
  1. ^ 1.0 1.1 Plakhotnik, V. N.; Varekh, V. V. Properties and solubility polytherm of nickel(II) tetrafluoroborate hexahydrate. Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya, 1973. 16 (11): 1619-1622. ISSN 0579-2991.
  2. ^ Ostrovskaya, T. V.; Amirova, S. A.; Startseva, N. V. Chemical transformations of iron, cobalt, and nickel tetrafluoroborates. Zhurnal Neorganicheskoi Khimii, 1967. 12 (9): 2327-2330. ISSN 0044-457X.
  3. ^ Morgunova, E. M.; Strezhnev, I. V.; Pinaevskaya, E. N.; Neganova, L. A.. Development of preparation technology for some fluoroborates. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970. 43 (5): 969-974. ISSN 0044-4618.
  4. ^ Plakhotnik, V. N.; Varekh, V. V. Hydrolysis of nickel tetrafluoroborate. Zhurnal Fizicheskoi Khimii, 1972. 46 (12): 3126-3129. ISSN 0044-4537.
  5. ^ Irene Bräunlich, Michael Medvedev, Julia Dshemuchadse, Michael Wörle, Walter Caseri. Trinuclear Complexes of Nickel(II) and 4-Amino-1,2,4-triazole: Trinuclear Complexes of Nickel(II) and 4-Amino-1,2,4-triazole. Zeitschrift für anorganische und allgemeine Chemie. 2015-10, 641 (12-13): 2344–2349 [2022-06-22]. doi:10.1002/zaac.201500234. (原始內容存檔於2022-06-22) (英語). 
  6. ^ Matthew G. Hilfiger, Michael Shatruk, Andrey Prosvirin, Kim R. Dunbar. Hexacyanoosmate(iii) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(ii). Chemical Communications. 2008, (44): 5752 [2022-06-22]. ISSN 1359-7345. doi:10.1039/b813413h (英語).