五疊氮化銻

五疊氮化銻
識別
CAS號	399041-55-5
SMILES	[N-]=[N+]=N[Sb](N=[N+]=[N-])(N=[N+]=[N-])(N=[N+]=[N-])N=[N+]=[N-];
性質
化學式	Sb(N3)5
摩爾質量	331.86 g·mol⁻¹
外觀	深黃色固體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

五疊氮化銻是一種無機化合物，化學式為Sb(N₃)₅，它具有三角雙錐構型，分子對稱性為C_s。^[2]它的合成最初於2002年被報道，即可由五氟化銻和三甲基疊氮矽烷在二氧化硫中反應得到，^[3]並於2004年被成功分離。^[1]它和疊氮化四苯基鏻反應，可以得到[PPh₄][Sb(N₃)₆]。^[1]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N₃)₅, Sb(N₃)₅, and [P(C₆H₅)₄][Sb(N₃)₆]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730.
^ 葛忠學, 丁可偉, 李陶琦. 多疊氮化合物（頁面存檔備份，存於互聯網檔案館）. 化學世界, 2012. 11: 965-700.
^ Karaghiosoff, Konstantin; Klapötke, Thomas M.; Krumm, Burkhard; Nöth, Heinrich; Schütt, Thomas; Suter, Max. Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species. Inorganic Chemistry (American Chemical Society (ACS)). 2001-12-22, 41 (2): 170–179. ISSN 0020-1669. doi:10.1021/ic010463l.

[angew-1] 1.0 ^1.1 ^1.2 Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N₃)₅, Sb(N₃)₅, and [P(C₆H₅)₄][Sb(N₃)₆]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730.

[hxsj-2] 葛忠學, 丁可偉, 李陶琦. 多疊氮化合物（頁面存檔備份，存於互聯網檔案館）. 化學世界, 2012. 11: 965-700.

[3] Karaghiosoff, Konstantin; Klapötke, Thomas M.; Krumm, Burkhard; Nöth, Heinrich; Schütt, Thomas; Suter, Max. Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species. Inorganic Chemistry (American Chemical Society (ACS)). 2001-12-22, 41 (2): 170–179. ISSN 0020-1669. doi:10.1021/ic010463l.

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