高氯酸釤

高氯酸釤
識別
CAS號	13569-60-3
性質
化學式	Cl3O12Sm
摩爾質量	448.71 g·mol−1
外觀	白色固體; 淺黃色晶體
溶解性（水）	可溶於水、乙醇（六水）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

高氯酸釤是一種無機化合物，化學式為Sm(ClO₄)₃。它可由高氯酸和氧化釤反應得到，^[3]從溶液中析出的水合物可用六氧化二氯對其脫水，得到無水物。^[1]無水高氯酸釤是六方晶系的晶體，空間群P63/m，晶胞參數a=9.259 Å，c=5.746 Å，Z=2。^[4]它和硫氰酸銨、1-丁基-3-甲基咪唑鎓硫氰酸鹽（[BMIM]SCN）在無水乙醇中反應，可以得到離子液體[BMIM]₄[Sm(NCS)₇(H₂O)]。^[5]

參考文獻[編輯]

^ ^1.0 ^1.1 Frédéric Favier, Jean-Louis Pascal. Synthesis and structural analysis of a homogeneous series of anhydrous rare-earth-metal perchlorates. Journal of the Chemical Society, Dalton Transactions. 1992, (13): 1997 [2021-11-05]. ISSN 0300-9246. doi:10.1039/dt9920001997 （英語）.
^ ^2.0 ^2.1 Jane E. Macintyre. Dictionary of Inorganic Compounds. CRC Press. 23 July 1992: 2930– [2023-03-15]. ISBN 978-0-412-30120-9. （原始內容存檔於2023-03-15）.
^ Mathias S. Wickleder, Wolfgang Schäfer. Synthesis and Structure of Anhydrous Rare-Earth Perchlorates M(ClO4)3 (M = La, Ce-Er, Y): Derivatives of the UCl3 Type of Structure. Zeitschrift für anorganische und allgemeine Chemie. 1999-02, 625 (2): 309–312 [2021-11-05]. ISSN 0044-2313. doi:10.1002/(SICI)1521-3749(199902)625:23.0.CO;2-6 （德語）.
^ J.L. Pascal, F. Favier, F. Cunin, A. Fitch, G. Vaughan. Crystalline and Molecular Structures of Anhydrous Lanthanide PerchloratesLn(ClO4)3withLn=La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu. Journal of Solid State Chemistry. 1998-09, 139 (2): 259–265 [2021-11-05]. doi:10.1006/jssc.1998.7838. （原始內容存檔於2018-06-05）（英語）.
^ Peter Nockemann, Ben Thijs, Niels Postelmans, Kristof Van Hecke, Luc Van Meervelt, Koen Binnemans. Anionic Rare-Earth Thiocyanate Complexes as Building Blocks for Low-Melting Metal-Containing Ionic Liquids. Journal of the American Chemical Society. 2006-10-01, 128 (42): 13658–13659 [2021-11-05]. ISSN 0002-7863. doi:10.1021/ja0640391. （原始內容存檔於2021-07-02）（英語）.

[dt-1] 1.0 ^1.1 Frédéric Favier, Jean-Louis Pascal. Synthesis and structural analysis of a homogeneous series of anhydrous rare-earth-metal perchlorates. Journal of the Chemical Society, Dalton Transactions. 1992, (13): 1997 [2021-11-05]. ISSN 0300-9246. doi:10.1039/dt9920001997 （英語）.

[Jane-2] 2.0 ^2.1 Jane E. Macintyre. Dictionary of Inorganic Compounds. CRC Press. 23 July 1992: 2930– [2023-03-15]. ISBN 978-0-412-30120-9. （原始內容存檔於2023-03-15）.

[3] Mathias S. Wickleder, Wolfgang Schäfer. Synthesis and Structure of Anhydrous Rare-Earth Perchlorates M(ClO4)3 (M = La, Ce-Er, Y): Derivatives of the UCl3 Type of Structure. Zeitschrift für anorganische und allgemeine Chemie. 1999-02, 625 (2): 309–312 [2021-11-05]. ISSN 0044-2313. doi:10.1002/(SICI)1521-3749(199902)625:23.0.CO;2-6 （德語）.

[4] J.L. Pascal, F. Favier, F. Cunin, A. Fitch, G. Vaughan. Crystalline and Molecular Structures of Anhydrous Lanthanide PerchloratesLn(ClO4)3withLn=La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu. Journal of Solid State Chemistry. 1998-09, 139 (2): 259–265 [2021-11-05]. doi:10.1006/jssc.1998.7838. （原始內容存檔於2018-06-05）（英語）.

[5] Peter Nockemann, Ben Thijs, Niels Postelmans, Kristof Van Hecke, Luc Van Meervelt, Koen Binnemans. Anionic Rare-Earth Thiocyanate Complexes as Building Blocks for Low-Melting Metal-Containing Ionic Liquids. Journal of the American Chemical Society. 2006-10-01, 128 (42): 13658–13659 [2021-11-05]. ISSN 0002-7863. doi:10.1021/ja0640391. （原始內容存檔於2021-07-02）（英語）.

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