1-萘甲醛
外觀
1-萘甲醛 | |
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識別 | |
CAS號 | 66-77-3 ![]() |
性質 | |
化學式 | C11H8O |
摩爾質量 | 156.18 g·mol−1 |
密度 | 1.066 g·cm−3(30 °C)[1] |
熔點 | 33.5 °C(307 K) |
沸點 | 292 °C(565 K) |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1-萘甲醛(英語:1-naphthaldehyde,或稱為α-萘甲醛,α-naphthaldehyde)是一種有機化合物,化學式為C11H8O。它可由1-萘甲醇的氧化反應製得。[2]它和丙二腈在甲醇中發生Knoevenagel反應,生成萘-1-亞甲基丙二腈。[3]它和四溴化碳在三苯基膦的存在下於二氯甲烷中反應,可以得到1-(2,2-二溴乙烯基)萘。[4]
參考文獻
[編輯]- ^ Bergmann, Ernst D.; Zimkin, E.; Pinchas, S. Reaction products of primary β-hydroxy amines with carbonyl compounds. II. Molecular refraction and infrared spectra. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique, 1952. 71: 168-191. ISSN: 0370-7539.
- ^ Rong-Bin Hu, Ying-Pong Lam, Wing-Hin Ng, Chun-Yuen Wong, Ying-Yeung Yeung. Zwitterion-Induced Organic–Metal Hybrid Catalysis in Aerobic Oxidation. ACS Catalysis. 2021-03-19, 11 (6): 3498–3506 [2021-05-08]. ISSN 2155-5435. doi:10.1021/acscatal.0c05684 (英語).
- ^ Biswajit Laha, Sadhika Khullar, Alisha Gogia, Sanjay K. Mandal. Effecting structural diversity in a series of Co( ii )–organic frameworks by the interplay between rigidity of a dicarboxylate and flexibility of bis(tridentate) spanning ligands. Dalton Transactions. 2020, 49 (35): 12298–12310 [2021-05-08]. ISSN 1477-9226. doi:10.1039/D0DT02153A (英語).
- ^ Takeshi Yamamoto, Aoi Ishibashi, Michinori Suginome. Rhodium-catalyzed C(sp 2 )–H Addition of Arylboronic Acids to Alkynes Using a Boron-based, Convertible ortho -Directing Group. Chemistry Letters. 2017-08-05, 46 (8): 1169–1172 [2021-05-08]. ISSN 0366-7022. doi:10.1246/cl.170404 (英語).