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三十六烷

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三十六烷
识别
CAS号 630-06-8  checkY
SMILES
 
  • CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC
性质
化学式 C36H74
摩尔质量 506.97 g·mol−1
密度 2.3 g·cm−3[1]
0.7819 g·cm−3(80 °C)[2]
熔点 76 °C(349 K)[3]
76.5 °C(349.6 K)[4]
沸点 298.4 °C(571.5 K)[4]
497.9 °C(771.0 K)[5]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三十六烷(英语:Hexatriacontane)是含有36个碳原子的直链烷烃,化学式为C36H74,外观为无色、透明的蜡状晶体。它理论上存在1.29530×1012同分异构体[6]它可由1-溴十八烷和金属钠反应制得。[7]

参考文献

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  1. ^ Thomas Lafitte, David Bessieres, Manuel M. Piñeiro, Jean-Luc Daridon. Simultaneous estimation of phase behavior and second-derivative properties using the statistical associating fluid theory with variable range approach. The Journal of Chemical Physics. 2006-01-14, 124 (2): 024509 [2020-11-06]. ISSN 0021-9606. doi:10.1063/1.2140276 (英语). 
  2. ^ Nametkin, S. S.; Nifontova, S. S.; Sushchik, R. Ya. Action of nitric acid on octadecane and hexatriacontane. Doklady Akademii Nauk SSSR, 1950. 70. 241-244. ISSN: 0002-3264.
  3. ^ Gascard, A. Three Normal Saturated Hydrocarbons: Triacontane, Tetratriacontane and Hexatriacontane. Compt. rend., 1912. 153. 1484-1487.
  4. ^ 4.0 4.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-11-06]
  5. ^ Jovan Jovanovic, Dusan Grozdanic. Reliable prediction of heat of vaporization of n-alkanes at 298.15 K. Journal of the Serbian Chemical Society. 2010, 75 (7): 997–1003 [2020-11-06]. ISSN 0352-5139. doi:10.2298/JSC091123067J. (原始内容存档于2020-08-26) (英语). 
  6. ^ Hans Lohninger. List of Alkanes. VIAS Library - General Chemistry. 2011-05-20 [2020-11-06]. (原始内容存档于2020-05-27). 
  7. ^ Process for preparation of highly purified linear alkanes with even carbon numbers. 2010. CN 101906008 A.