三碘化铯
外观
三碘化铯 | |
---|---|
识别 | |
CAS号 | 12297-72-2 |
性质 | |
化学式 | CsI3 |
摩尔质量 | 513.62 g·mol−1 |
外观 | 紫色[1] |
熔点 | 77 °C(分解)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三碘化铯是一种无机化合物,化学式为CsI3。它可由碘化铯和碘在乙醇水溶液中缓慢挥发,结晶得到。[3]它可以和重氮苯形成沉淀。[4]
它在高压下发生相变,从Pnma转变为P-3c1,其结构由层状变为3D。[5]
参考文献
[编辑]- ^ Ronald Rich. Inorganic Reactions in Water. Springer. 22 December 2007: 472 [2022-09-12]. ISBN 978-3-540-73962-3. (原始内容存档于2022-09-12).
- ^ G.S. Harris, J.S. McKechnie. Thermogravimetric analysis and dissociation pressure of caesium tribalides. Polyhedron. 1982-01, 1 (2): 215–216 [2022-09-09]. doi:10.1016/S0277-5387(00)80991-2. (原始内容存档于2018-06-09) (英语).
- ^ Richard M. Bozorth, Linus Pauling. THE CRYSTAL STRUCTURES OF CESIUM TRI-IODIDE AND CESIUM DIBROMO-IODIDE. Journal of the American Chemical Society. 1925-06, 47 (6): 1561–1571 [2022-09-09]. ISSN 0002-7863. doi:10.1021/ja01683a009. (原始内容存档于2022-09-09) (英语).
- ^ H. F. Halliwell, S. C. Nyburg. 891. The reaction of the benzenediazonium ion with certain anions in aqueous acid solution. Journal of the Chemical Society (Resumed). 1960: 4603 [2022-09-09]. ISSN 0368-1769. doi:10.1039/jr9600004603 (英语).
- ^ Tomasz Porȩba, Stefano Racioppi, Gaston Garbarino, Wolfgang Morgenroth, Mohamed Mezouar. Investigating the Structural Symmetrization of CsI 3 at High Pressures through Combined X-ray Diffraction Experiments and Theoretical Analysis. Inorganic Chemistry. 2022-07-18, 61 (28): 10977–10985 [2022-09-09]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.2c01690. (原始内容存档于2022-09-09) (英语).