2-氯丁烷
外观
2-氯丁烷 | |
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别名 | 氯代仲丁烷 仲丁基氯 |
识别 | |
CAS号 | 78-86-4 ![]() 22157-31-9((R)) ![]() 22156-91-8((S)) ![]() |
PubChem | 6563 23616278((R)) 637146((S)) |
ChemSpider | 6315, 19952591 (R), 552795 (S) |
SMILES |
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InChI |
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InChIKey | BSPCSKHALVHRSR-UHFFFAOYSA-N |
EINECS | 201-151-7 |
ChEBI | 166855 |
性质 | |
化学式 | C4H9Cl |
摩尔质量 | 92.57 g·mol−1 |
密度 | 0.873 g·cm−3 |
熔点 | -140 °C(133 K) |
沸点 | 68 °C(341 K) |
磁化率 | -67.40·10−6 cm3/mol |
危险性 | |
GHS危险性符号![]() ![]() | |
GHS提示词 | Danger |
H-术语 | H225, H315, H319, H335 |
P-术语 | P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+352, P303+361+353, P304+340, P305+351+338 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
2-氯丁烷是一种有机氯化合物,化学式为C4H9Cl。它是无色挥发性液体,有卤代烃的气味。 它可由2-丁醇在氯化锌的存在下和浓盐酸反应得到,[1]此外,在三苯基膦的存在下,四氯化碳也可作为氯化试剂,将2-丁醇转化为2-氯丁烷。[2]它和叠氮化钠在二甲基甲酰胺中反应,可以得到2-叠氮基丁烷。[3]它和镁在乙醚中反应,可以得到2-丁基氯化镁[4];和锂反应,得到2-丁基锂。[5]
参考文献
[编辑]- ^ Arthur I. Vogel. 169. Physical properties and chemical constitution. Part VIII. Alkyl chlorides, bromides, and iodides. Journal of the Chemical Society (Resumed). 1943: 636 [2021-01-18]. ISSN 0368-1769. doi:10.1039/jr9430000636 (英语).
- ^ Bertrand R. Castro. John Wiley & Sons, Inc. , 编. Replacement of Alcoholic Hydroxyl Groups by Halogens and Other Nucleophiles via Oxyphosphonium Intermediates. Hoboken, NJ, USA: John Wiley & Sons, Inc. 1983-07-27: 1–162 [2021-01-18]. ISBN 9780471264187. doi:10.1002/0471264180.or029.01 (英语).
- ^ Kishore Kumar Angajala, Sunitha Vianala, Ramesh Macha, M. Raghavender, Murali Krishna Thupurani, P. J. Pathi. Synthesis, anti-inflammatory, bactericidal activities and docking studies of novel 1,2,3-triazoles derived from ibuprofen using click chemistry. SpringerPlus. 2016-12, 5 (1) [2021-01-18]. ISSN 2193-1801. doi:10.1186/s40064-016-2052-5. (原始内容存档于2018-06-02) (英语).
- ^ O. G. Yarosh, M. G. Voronkov, L. V. Zhilitskaya, N. O. Yarosh, A. I. Albanov, I. M. Korotaeva. Organomagnesium Synthesis of sec-Butyl- and tert-Alkylchlorogermanes and Their Reaction with Ethynylmagnesium Bromide. Russian Journal of General Chemistry. 2005-05, 75 (5): 714–718 [2021-01-18]. ISSN 1070-3632. doi:10.1007/s11176-005-0305-z (英语).
- ^ Dieter, R. Karl. Product subclass 1: Lithium metal. Science of Synthesis, 2006. 8a. 43-132. CODEN: SSCYJ9.