叠氮化铋

叠氮化铋
识别
CAS号	115834-32-7
性质
化学式	Bi(N3)3
外观	黄色晶体或浅黄色固体; 无色固体（四氢呋喃合物）
熔点	154 °C（爆炸）; 248 °C（四氢呋喃合物，分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

叠氮化铋是一种无机化合物，化学式为Bi(N₃)₃，对撞击和摩擦敏感^[1]。它最早由Thomas M. Klapötke和Axel Schulz于1997年通过碘化铋和叠氮化银在乙腈中的反应制得并由红外表征，产物无法和同时生成的碘化银分离。^[4]2010年，Alexander Villinger和Axel Schulz通过三氟化铋和三甲基叠氮硅烷的反应制得了纯净的叠氮化铋。^[3]它的多种溶剂合物是已知的。^[1]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 Rosenstengel, Kati; Schulz, Axel; Villinger, Alexander. Solid State Structure of Bi(N₃)₃, Bi(N₃)₃·Solvates and the Structural Dynamics in the [Bi(N₃)₆]^3– Anion. Inorganic Chemistry (American Chemical Society (ACS)). 2013-05-09, 52 (10): 6110–6126. ISSN 0020-1669. doi:10.1021/ic400493v.
^ Haiges, Ralf; Rahm, Martin; Dixon, David A.; Garner, Edward B.; Christe, Karl O. Binary Group 15 Polyazides. Structural Characterization of [Bi(N₃)₄]⁻, [Bi(N₃)₅]^2–, [bipy·Bi(N₃)₅]^2–, [Bi(N₃)₆]^3–, bipy·As(N₃)₃, bipy·Sb(N₃)₃, and [(bipy)₂·Bi(N₃)₃]₂ and on the Lone Pair Activation of Valence Electrons. Inorganic Chemistry (American Chemical Society (ACS)). 2011-12-23, 51 (2): 1127–1141. ISSN 0020-1669. doi:10.1021/ic202307a.
^ ^3.0 ^3.1 ^3.2 Villinger, Alexander; Schulz, Axel. Binary Bismuth(III) Azides: Bi(N₃)₃ , [Bi(N₃)₄]⁻, and [Bi(N₃)₆]³⁻. Angewandte Chemie International Edition (Wiley). 2010-09-13, 49 (43): 8017–8020. ISSN 1433-7851. doi:10.1002/anie.201002179.
^ Klapötke, Thomas M.; Schulz, Axel. GROUP 15 TRIAZIDES: A COMPREHENSIVE THEORETICAL STUDY AND THE PREPARATION OF BISMUTH TRIAZIDE. Main Group Metal Chemistry (Walter de Gruyter GmbH). 1997, 20 (5). ISSN 2191-0219. doi:10.1515/mgmc.1997.20.5.325.

[ic-1] 1.0 ^1.1 ^1.2 Rosenstengel, Kati; Schulz, Axel; Villinger, Alexander. Solid State Structure of Bi(N₃)₃, Bi(N₃)₃·Solvates and the Structural Dynamics in the [Bi(N₃)₆]^3– Anion. Inorganic Chemistry (American Chemical Society (ACS)). 2013-05-09, 52 (10): 6110–6126. ISSN 0020-1669. doi:10.1021/ic400493v.

[2] Haiges, Ralf; Rahm, Martin; Dixon, David A.; Garner, Edward B.; Christe, Karl O. Binary Group 15 Polyazides. Structural Characterization of [Bi(N₃)₄]⁻, [Bi(N₃)₅]^2–, [bipy·Bi(N₃)₅]^2–, [Bi(N₃)₆]^3–, bipy·As(N₃)₃, bipy·Sb(N₃)₃, and [(bipy)₂·Bi(N₃)₃]₂ and on the Lone Pair Activation of Valence Electrons. Inorganic Chemistry (American Chemical Society (ACS)). 2011-12-23, 51 (2): 1127–1141. ISSN 0020-1669. doi:10.1021/ic202307a.

[angew-3] 3.0 ^3.1 ^3.2 Villinger, Alexander; Schulz, Axel. Binary Bismuth(III) Azides: Bi(N₃)₃ , [Bi(N₃)₄]⁻, and [Bi(N₃)₆]³⁻. Angewandte Chemie International Edition (Wiley). 2010-09-13, 49 (43): 8017–8020. ISSN 1433-7851. doi:10.1002/anie.201002179.

[4] Klapötke, Thomas M.; Schulz, Axel. GROUP 15 TRIAZIDES: A COMPREHENSIVE THEORETICAL STUDY AND THE PREPARATION OF BISMUTH TRIAZIDE. Main Group Metal Chemistry (Walter de Gruyter GmbH). 1997, 20 (5). ISSN 2191-0219. doi:10.1515/mgmc.1997.20.5.325.

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