四羰基(三苯基膦)合铁

四羰基(三苯基膦)合铁
识别
CAS号	14649-69-5
性质
化学式	C22H15FeO4P
摩尔质量	430.17 g·mol−1
外观	黄色晶体
密度	1.41 g·cm−3（19 °C）
熔点	200—204 °C（473—477 K）（分解）
沸点	185 °C（真空，升华）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四羰基(三苯基膦)合铁是一种有机铁化合物，化学式为[(C₆H₅)₃P]Fe(CO)₄。它可由五羰基铁和三苯基膦在汞灯照射下于环己烷中（或钯催化下于甲苯中^[4]）反应得到^[5]；它也可以在三羰基(1,3-丁二烯)合铁和三苯基膦在40 °C的反应中生成。^[6]它和SnX₄反应，可以得到Fe(CO)₃X[P(C₆H₅)₃]SnX₃（X=Cl, Br）。^[7]

参考文献[编辑]

^ ^1.0 ^1.1 K. Farmery, M. Kilner. Substitution reactions of dihydridotetracarbonyliron. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1970: 634 [2023-03-10]. ISSN 0022-4944. doi:10.1039/j19700000634 （英语）.
^ Paul E. Riley, Raymond E. Davis. Crystal structures at -35.degree.C of tetraphenylphosphonium (triphenylphosphine)tetracarbonylmanganate and (triphenylphosphine)tetracarbonyliron. Inorganic Chemistry. 1980-01, 19 (1): 159–165 [2023-03-10]. ISSN 0020-1669. doi:10.1021/ic50203a033. （原始内容存档于2023-03-10）（英语）.
^ R.J. Angelici, E.E. Siefert. Substitution reactions of trigonal bipyramidal complexes of iron pentacarbonyl. Journal of Organometallic Chemistry. 1967-05, 8 (2): 374–376 [2023-03-10]. doi:10.1016/S0022-328X(00)91055-6. （原始内容存档于2018-06-30）（英语）.
^ Michel O. Albers, Neil J. Coville, Eric Singleton. The use of supported transition metals and metal oxides as catalysts for the metal carbonyl substitution reaction. Journal of the Chemical Society, Chemical Communications. 1982, (2): 96 [2023-03-10]. ISSN 0022-4936. doi:10.1039/c39820000096 （英语）.
^ Lewis, J.; Nyholm, R. S.; Sandhu, S. S.; Stiddard, M. H. B.. Photochemically-induced substitution reactions of pentacarbonyliron. Journal of the Chemical Society Aug. 1964: 2825-2827. ISSN 0368-1769
^ Murdoch, H. D.; Weiss, E. Butadieneiron carbonyl compounds. Helvetica Chimica Acta, 1962. 45: 1156-1161.
^ Tetsuo Takano. The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls. Bulletin of the Chemical Society of Japan. 1973-02, 46 (2): 522–523 [2023-03-10]. ISSN 0009-2673. doi:10.1246/bcsj.46.522. （原始内容存档于2023-03-10）（英语）.

参见[编辑]

三羰基二(三苯基膦)合铁

[Farmery-1] 1.0 ^1.1 K. Farmery, M. Kilner. Substitution reactions of dihydridotetracarbonyliron. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1970: 634 [2023-03-10]. ISSN 0022-4944. doi:10.1039/j19700000634 （英语）.

[2] Paul E. Riley, Raymond E. Davis. Crystal structures at -35.degree.C of tetraphenylphosphonium (triphenylphosphine)tetracarbonylmanganate and (triphenylphosphine)tetracarbonyliron. Inorganic Chemistry. 1980-01, 19 (1): 159–165 [2023-03-10]. ISSN 0020-1669. doi:10.1021/ic50203a033. （原始内容存档于2023-03-10）（英语）.

[3] R.J. Angelici, E.E. Siefert. Substitution reactions of trigonal bipyramidal complexes of iron pentacarbonyl. Journal of Organometallic Chemistry. 1967-05, 8 (2): 374–376 [2023-03-10]. doi:10.1016/S0022-328X(00)91055-6. （原始内容存档于2018-06-30）（英语）.

[4] Michel O. Albers, Neil J. Coville, Eric Singleton. The use of supported transition metals and metal oxides as catalysts for the metal carbonyl substitution reaction. Journal of the Chemical Society, Chemical Communications. 1982, (2): 96 [2023-03-10]. ISSN 0022-4936. doi:10.1039/c39820000096 （英语）.

[5] Lewis, J.; Nyholm, R. S.; Sandhu, S. S.; Stiddard, M. H. B.. Photochemically-induced substitution reactions of pentacarbonyliron. Journal of the Chemical Society Aug. 1964: 2825-2827. ISSN 0368-1769

[6] Murdoch, H. D.; Weiss, E. Butadieneiron carbonyl compounds. Helvetica Chimica Acta, 1962. 45: 1156-1161.

[7] Tetsuo Takano. The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls. Bulletin of the Chemical Society of Japan. 1973-02, 46 (2): 522–523 [2023-03-10]. ISSN 0009-2673. doi:10.1246/bcsj.46.522. （原始内容存档于2023-03-10）（英语）.

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