磷化铈

磷化铈是一种无机化合物，化学式为CeP，它是铈的磷化物之一。它可由二氧化铈和磷化氢在氢气的存在下于1300 °C反应得到，^[2]或由磷化钠和氯化铈在700~800 °C反应得到。^[1]它在空气中在900 °C以上会氧化为单斜的CePO₄。^[2]它在石英安瓿内和碘反应，可以得到CeSiP₃。^[3]

参考文献[编辑]

^ ^1.0 ^1.1 Rowley, Adrian T.; Parkin, Ivan P. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry (Royal Society of Chemistry (RSC)). 1993, 3 (7): 689. ISSN 0959-9428. doi:10.1039/jm9930300689.
^ ^2.0 ^2.1 Vasil'eva, I. G.; Mironov, K. E.; Mironov, Yu. I. Properties of cerium monophosphide（俄文）. Redkozemel. Metal. Ikh Soedin., Mater. Vses. Simp., 1970: 160-165. CODEN 26HIAV.
^ Mironov, K. E.; Abdullin, R. V. Formation and chemical transfer of cerium silicon phosphide (CeSiP3)（俄文）. Zhurnal Neorganicheskoi Khimii, 1980. 25 (8): 2062-2066.

Pavel S. Chizhov, Nellie R. Khasanova, Michael Baitinger, Walter Schnelle, Yuri Prots, Ulrich Burkhardt, Evgeny V. Antipov, Yuri Grin. Ce 4 (P 1- x Si x ) 3- z : A First Example for the Stabilization of the Anti-Th 3 P 4 Type Structure by Substitution in the Non-Metal Substructure. Inorganic Chemistry. 2006-09-01, 45 (18): 7210–7216 [2021-12-27]. ISSN 0020-1669. doi:10.1021/ic060726h （英语）.