螺戊烷

螺戊烷
	IUPAC名; Spiro[2.2]pentane
别名	螺[2.2]戊烷
识别
CAS号	157-40-4
PubChem	9088
ChemSpider	8734
SMILES	C1CC12CC2;
性质
化学式	C5H8
摩尔质量	68.12 g·mol−1
熔点	-134.6 °C（139 K）
沸点	39.0 °C（312 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

螺戊烷是一种三角烷（英语：triangulane）类有机物，化学式为C
5H
8，它是最简单的螺环烷烃。^[1]^[2]^[3]^[4]它最早于1887年被发现，数年后其分子结构得到标准。^[5]^[6]^[7] 它在200 °C分解，对其于360~410 °C热解，会扩环得到其异构体亚甲基环丁烷，并同时生成乙烯和丙二烯。^[8]

参考文献[编辑]

^ Donohue, Jerry; Humphrey, George L.; Schomaker, Verner. The Structure of Spiropentane. Journal of the American Chemical Society. 1945, 67 (2): 332–335. ISSN 0002-7863. doi:10.1021/ja01218a056.
^ Murray, M. J.; Stevenson, Eugene H. SPIROPENTANE. Journal of the American Chemical Society. 1944, 66 (2): 314. ISSN 0002-7863. doi:10.1021/ja01230a515.
^ Murray, M. J.; Stevenson, Eugene H. The Debromination of Pentaerythrityl Bromide by Zinc. Isolation of Spiropentane1. Journal of the American Chemical Society. 1944, 66 (5): 812–816. ISSN 0002-7863. doi:10.1021/ja01233a047.
^ Price, J.E.; Coulterpark, K.A.; Masiello, T.; Nibler, J.W.; Weber, A.; Maki, A.; Blake, T.A. High-resolution infrared spectra of spiropentane, C5H8. Journal of Molecular Spectroscopy. 2011, 269 (1): 129–136. Bibcode:2011JMoSp.269..129P. ISSN 0022-2852. doi:10.1016/j.jms.2011.05.011.
^ Philipow, O. Die Konstitution der Kohlenwasserstoffe Gustavsons: Vinyltrimethylen und Äthylidentrimethylen. Journal für Praktische Chemie. 1916, 93 (1): 162–182 [2023-11-20]. ISSN 0021-8383. doi:10.1002/prac.19160930112. （原始内容存档于2021-06-29）.
^ Faworsky, Al.; Batalin, W. Über das Vinyltrimethylen und Äthyliden-trimethylen von Gustavson. Berichte der Deutschen Chemischen Gesellschaft. 1914, 47 (2): 1648–1651 [2023-11-20]. ISSN 0365-9496. doi:10.1002/cber.19140470250. （原始内容存档于2021-06-29）.
^ Burns, G. R.; McGavin, D. G. Infrared and Raman Spectra of Spiropentane-H8. Applied Spectroscopy. 1972, 26 (5): 540–542. Bibcode:1972ApSpe..26..540B. S2CID 95384874. doi:10.1366/000370272774351778.
^ J. J. Gajewski, L. T. Burka, Journal of the American Chemical Society 94, Nr. 25, 8857 (1972).

[DonohueHumphrey1945-1] Donohue, Jerry; Humphrey, George L.; Schomaker, Verner. The Structure of Spiropentane. Journal of the American Chemical Society. 1945, 67 (2): 332–335. ISSN 0002-7863. doi:10.1021/ja01218a056.

[MurrayStevenson1944a-2] Murray, M. J.; Stevenson, Eugene H. SPIROPENTANE. Journal of the American Chemical Society. 1944, 66 (2): 314. ISSN 0002-7863. doi:10.1021/ja01230a515.

[MurrayStevenson1944b-3] Murray, M. J.; Stevenson, Eugene H. The Debromination of Pentaerythrityl Bromide by Zinc. Isolation of Spiropentane1. Journal of the American Chemical Society. 1944, 66 (5): 812–816. ISSN 0002-7863. doi:10.1021/ja01233a047.

[PriceCoulterpark2011-4] Price, J.E.; Coulterpark, K.A.; Masiello, T.; Nibler, J.W.; Weber, A.; Maki, A.; Blake, T.A. High-resolution infrared spectra of spiropentane, C5H8. Journal of Molecular Spectroscopy. 2011, 269 (1): 129–136. Bibcode:2011JMoSp.269..129P. ISSN 0022-2852. doi:10.1016/j.jms.2011.05.011.

[Philipow1916-5] Philipow, O. Die Konstitution der Kohlenwasserstoffe Gustavsons: Vinyltrimethylen und Äthylidentrimethylen. Journal für Praktische Chemie. 1916, 93 (1): 162–182 [2023-11-20]. ISSN 0021-8383. doi:10.1002/prac.19160930112. （原始内容存档于2021-06-29）.

[FaworskyBatalin1914-6] Faworsky, Al.; Batalin, W. Über das Vinyltrimethylen und Äthyliden-trimethylen von Gustavson. Berichte der Deutschen Chemischen Gesellschaft. 1914, 47 (2): 1648–1651 [2023-11-20]. ISSN 0365-9496. doi:10.1002/cber.19140470250. （原始内容存档于2021-06-29）.

[burns-7] Burns, G. R.; McGavin, D. G. Infrared and Raman Spectra of Spiropentane-H8. Applied Spectroscopy. 1972, 26 (5): 540–542. Bibcode:1972ApSpe..26..540B. S2CID 95384874. doi:10.1366/000370272774351778.

[Gajewski-8] J. J. Gajewski, L. T. Burka, Journal of the American Chemical Society 94, Nr. 25, 8857 (1972).

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