高氯酸镓

高氯酸镓是一种无机化合物，化学式为Ga(ClO₄)₃。它可由氧化镓和高氯酸反应制得，从溶液中可以析出水合物。^[1]三氯化镓和高氯酸银在甲醇中反应，可以得到无水高氯酸镓。^[2]它可用作α-羟基酮和邻苯二胺的环加成反应的催化剂。^[3]

参考文献[编辑]

^ Laurence S. Foster. (I) The Reaction of Gallium with Perchloric Acid and (II) the Preparation and Properties of Gallium Perchlorate Hydrates. Journal of the American Chemical Society. 1939-11, 61 (11): 3122–3124 [2021-11-27]. ISSN 0002-7863. doi:10.1021/ja01266a041. （原始内容存档于2021-11-27）（英语）.
^ Haladjian, J.; Bianco, P. Preparation of aluminum, gallium, and indium anhydrous perchlorates in methanolic solution（法文）. Chimia, 1973 (27) 11: 588-589.
^ Fan Pan, Tang-Ming Chen, Jia-Jia Cao, Jian-Ping Zou, Wei Zhang. Ga(ClO4)3-catalyzed synthesis of quinoxalines by cycloaddition of α-hydroxyketones and o-phenylenediamines. Tetrahedron Letters. 2012-05, 53 (20): 2508–2510 [2021-11-27]. doi:10.1016/j.tetlet.2012.02.113. （原始内容存档于2018-06-23）（英语）.

Babakulov, N.; Grigor'eva, E. G.; Latysheva, V. A. Speed of sound and compressibility of aqueous solutions of some Group II and Group III metal perchlorates（俄文）. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1977. 50 (2): 467. ISSN 0044-4618.