2-甲基十三烷

2-甲基十三烷
英文名	2-Methyltridecane
识别
CAS号	1560-96-9
PubChem	15269
ChemSpider	14534
SMILES	CC(C)CCCCCCCCCCC;
ChEBI	84277
性质
化学式	C14H30
摩尔质量	198.39 g·mol−1
熔点	−21 °C（252 K）
沸点	121.5 °C（394.6 K）（12 Torr）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2-甲基十三烷是一种有机化合物，化学式为 ${\ce {C14H30}}$ ，它是十四烷的同分异构体之一。它可由2,2-二甲基-3-癸基环硫乙烷的还原反应制备。^[3]金属镧在四氢呋喃中还原2-碘代-2-甲基十三烷，可以得到2-甲基十三烷，副产物包括12,12,13,13-四甲基二十四烷及一些烯烃产物。^[4]雷尼镍加氢还原13-溴-2-甲基十三烷-2-醇也会得到少许的2-甲基十三烷。^[5]

参考文献[编辑]

^ Petrov, A. D. Synthesis and properties of branched C12-C24 paraffins. Doklady - Akademiya Nauk Azerbaidzhanskoi SSR, 1955. 11 (11): 747-755. ISSN: 0002-3078.
^ Petrov, Al. A.; Sergienko, S. R.; Nechitailo, N. A.; Tsedilina, A. L. Synthesis and properties of monomethyl alkanes of composition C12-16. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959. 1091-1097. ISSN: 0002-3353.
^ J.R. Schauder, J.N. Denis, A. Krief. Reduction of thiiranes to alkenes and alkanes. Tetrahedron Letters. 1983, 24 (15): 1657–1660 [2020-06-10]. doi:10.1016/S0040-4039(00)81737-2. （原始内容存档于2018-06-09）（英语）.
^ Toshiki Nishino, Toshihisa Watanabe, Mitsuo Okada, Yutaka Nishiyama, Noboru Sonoda. Reduction of Organic Halides with Lanthanum Metal: A Novel Generation Method of Alkyl Radicals. The Journal of Organic Chemistry. 2002-02, 67 (3): 966–969 [2020-06-10]. ISSN 0022-3263. doi:10.1021/jo016205n. （原始内容存档于2019-04-03）（英语）.
^ Marie E. Krafft, William J. Crooks. Deoxygenation of tertiary alcohols using Raney nickel. The Journal of Organic Chemistry. 1988-01, 53 (2): 432–434 [2020-06-10]. ISSN 0022-3263. doi:10.1021/jo00237a041 （英语）.

[1] Petrov, A. D. Synthesis and properties of branched C12-C24 paraffins. Doklady - Akademiya Nauk Azerbaidzhanskoi SSR, 1955. 11 (11): 747-755. ISSN: 0002-3078.

[2] Petrov, Al. A.; Sergienko, S. R.; Nechitailo, N. A.; Tsedilina, A. L. Synthesis and properties of monomethyl alkanes of composition C12-16. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959. 1091-1097. ISSN: 0002-3353.

[3] J.R. Schauder, J.N. Denis, A. Krief. Reduction of thiiranes to alkenes and alkanes. Tetrahedron Letters. 1983, 24 (15): 1657–1660 [2020-06-10]. doi:10.1016/S0040-4039(00)81737-2. （原始内容存档于2018-06-09）（英语）.

[4] Toshiki Nishino, Toshihisa Watanabe, Mitsuo Okada, Yutaka Nishiyama, Noboru Sonoda. Reduction of Organic Halides with Lanthanum Metal: A Novel Generation Method of Alkyl Radicals. The Journal of Organic Chemistry. 2002-02, 67 (3): 966–969 [2020-06-10]. ISSN 0022-3263. doi:10.1021/jo016205n. （原始内容存档于2019-04-03）（英语）.

[5] Marie E. Krafft, William J. Crooks. Deoxygenation of tertiary alcohols using Raney nickel. The Journal of Organic Chemistry. 1988-01, 53 (2): 432–434 [2020-06-10]. ISSN 0022-3263. doi:10.1021/jo00237a041 （英语）.

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