肉桂基溴

肉桂基溴
别名	苯丙烯基溴
识别
CAS号	4392-24-9 ; 26146-77-0（反式） ; 115117-88-9（顺式）
性质
化学式	C9H9Br
摩尔质量	197.07 g·mol−1
熔点	26—28 °C（299—301 K）（反式）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

肉桂基溴是一种有机溴化合物，化学式为C₉H₉Br，它存在顺、反异构体，其中，反式异构体更为常见。

肉桂基溴可由肉桂醇和三溴化磷反应制得。^[2]它和叠氮化钠反应，可以得到肉桂基叠氮化物。^[3]^[4]它和乙酸钾在DMSO中反应，可以得到乙酸肉桂酯。^[5]

参考文献[编辑]

^ Y. Tamaru, Y. Furukawa, M. Mizutani, O. Kitao, Z. Yoshida. Diastereoselective .alpha. allylation of secondary and tertiary thioamides via thio-Claisen rearrangement. A structural proof of Z secondary thioamide dianions and Z tertiary thioamide anions. The Journal of Organic Chemistry. 1983-10, 48 (21): 3631–3639 [2023-03-25]. ISSN 0022-3263. doi:10.1021/jo00169a003. （原始内容存档于2023-03-25）（英语）.
^ Hong-Fa Wang, Lin-Na Guo, Zhi-Bo Fan, Tian-Hua Tang, Weiwei Zi. Gold-Catalyzed Formal Hexadehydro-Diels–Alder/Carboalkoxylation Reaction Cascades. Organic Letters. 2021-04-02, 23 (7): 2676–2681 [2023-03-25]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c00581. （原始内容存档于2022-11-20）（英语）.
^ Lachlan Campbell-Verduyn, Philip H. Elsinga, Leila Mirfeizi, Rudi A. Dierckx, Ben L. Feringa. Copper-free ‘click’: 1,3-dipolar cycloaddition of azides and arynes. Organic & Biomolecular Chemistry. 2008, 6 (19): 3461 [2023-03-25]. ISSN 1477-0520. doi:10.1039/b812403e （英语）.
^ Feng Shi, Jesse P. Waldo, Yu Chen, Richard C. Larock. Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides. Organic Letters. 2008-06-01, 10 (12): 2409–2412 [2023-03-25]. ISSN 1523-7060. PMC 3750119 . PMID 18476707. doi:10.1021/ol800675u. （原始内容存档于2023-03-25）（英语）.
^ Natan J. W. Straathof, Sten E. Cramer, Volker Hessel, Timothy Noël. Practical Photocatalytic Trifluoromethylation and Hydrotrifluoromethylation of Styrenes in Batch and Flow. Angewandte Chemie International Edition. 2016-12-12, 55 (50): 15549–15553 [2023-03-25]. doi:10.1002/anie.201608297. （原始内容存档于2023-03-25）（英语）.

[1] Y. Tamaru, Y. Furukawa, M. Mizutani, O. Kitao, Z. Yoshida. Diastereoselective .alpha. allylation of secondary and tertiary thioamides via thio-Claisen rearrangement. A structural proof of Z secondary thioamide dianions and Z tertiary thioamide anions. The Journal of Organic Chemistry. 1983-10, 48 (21): 3631–3639 [2023-03-25]. ISSN 0022-3263. doi:10.1021/jo00169a003. （原始内容存档于2023-03-25）（英语）.

[2] Hong-Fa Wang, Lin-Na Guo, Zhi-Bo Fan, Tian-Hua Tang, Weiwei Zi. Gold-Catalyzed Formal Hexadehydro-Diels–Alder/Carboalkoxylation Reaction Cascades. Organic Letters. 2021-04-02, 23 (7): 2676–2681 [2023-03-25]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c00581. （原始内容存档于2022-11-20）（英语）.

[3] Lachlan Campbell-Verduyn, Philip H. Elsinga, Leila Mirfeizi, Rudi A. Dierckx, Ben L. Feringa. Copper-free ‘click’: 1,3-dipolar cycloaddition of azides and arynes. Organic & Biomolecular Chemistry. 2008, 6 (19): 3461 [2023-03-25]. ISSN 1477-0520. doi:10.1039/b812403e （英语）.

[4] Feng Shi, Jesse P. Waldo, Yu Chen, Richard C. Larock. Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides. Organic Letters. 2008-06-01, 10 (12): 2409–2412 [2023-03-25]. ISSN 1523-7060. PMC 3750119 . PMID 18476707. doi:10.1021/ol800675u. （原始内容存档于2023-03-25）（英语）.

[5] Natan J. W. Straathof, Sten E. Cramer, Volker Hessel, Timothy Noël. Practical Photocatalytic Trifluoromethylation and Hydrotrifluoromethylation of Styrenes in Batch and Flow. Angewandte Chemie International Edition. 2016-12-12, 55 (50): 15549–15553 [2023-03-25]. doi:10.1002/anie.201608297. （原始内容存档于2023-03-25）（英语）.

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