肉桂基溴[编辑]
外观
肉桂基溴 | |
---|---|
别名 | 苯丙烯基溴 |
识别 | |
CAS号 | 4392-24-9 26146-77-0(反式) 115117-88-9(顺式) |
性质 | |
化学式 | C9H9Br |
摩尔质量 | 197.07 g·mol−1 |
熔点 | 26—28 °C(299—301 K)(反式)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
肉桂基溴是一种有机溴化合物,化学式为C9H9Br,它存在顺、反异构体,其中,反式异构体更为常见。
肉桂基溴可由肉桂醇和三溴化磷反应制得。[2]它和叠氮化钠反应,可以得到肉桂基叠氮化物。[3][4]它和乙酸钾在DMSO中反应,可以得到乙酸肉桂酯。[5]
参考文献
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- ^ Hong-Fa Wang, Lin-Na Guo, Zhi-Bo Fan, Tian-Hua Tang, Weiwei Zi. Gold-Catalyzed Formal Hexadehydro-Diels–Alder/Carboalkoxylation Reaction Cascades. Organic Letters. 2021-04-02, 23 (7): 2676–2681 [2023-03-25]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c00581. (原始内容存档于2022-11-20) (英语).
- ^ Lachlan Campbell-Verduyn, Philip H. Elsinga, Leila Mirfeizi, Rudi A. Dierckx, Ben L. Feringa. Copper-free ‘click’: 1,3-dipolar cycloaddition of azides and arynes. Organic & Biomolecular Chemistry. 2008, 6 (19): 3461 [2023-03-25]. ISSN 1477-0520. doi:10.1039/b812403e (英语).
- ^ Feng Shi, Jesse P. Waldo, Yu Chen, Richard C. Larock. Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides. Organic Letters. 2008-06-01, 10 (12): 2409–2412 [2023-03-25]. ISSN 1523-7060. PMC 3750119 . PMID 18476707. doi:10.1021/ol800675u. (原始内容存档于2023-03-25) (英语).
- ^ Natan J. W. Straathof, Sten E. Cramer, Volker Hessel, Timothy Noël. Practical Photocatalytic Trifluoromethylation and Hydrotrifluoromethylation of Styrenes in Batch and Flow. Angewandte Chemie International Edition. 2016-12-12, 55 (50): 15549–15553 [2023-03-25]. doi:10.1002/anie.201608297. (原始内容存档于2023-03-25) (英语).