跳转到内容

1-十三烷醇

维基百科,自由的百科全书
1-十三烷醇
IUPAC名
Tridecan-1-ol
别名 十三醇
1-十三醇
正十三醇
识别
CAS号 112-70-9  checkY
PubChem 8207
ChemSpider 7915
SMILES
 
  • CCCCCCCCCCCCCO
InChI
 
  • 1/C13H28O/c1-2-3-4-5-6-7-8-9-10-11-12-13/h13H,2-13H2,1H3
InChIKey needed
性质
化学式 C13H28O
摩尔质量 200.36 g·mol−1
外观 白色固体[1]
密度 0.84 g/cm3[1]
熔点 33 °C(306 K)[2]
沸点 274—280 °C(547—553 K)[1]
溶解性 难溶[1]
危险性
致死量或浓度:
LD50中位剂量
17200 mg/kg (rat, oral)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1-十三烷醇是一种有机化合物,化学式为C13H28O。它可由十三酸在催化下经氢气还原制得。[3]三苯基磷咪唑存在下,它和反应,可以得到1-碘十三烷。[4]吡啶氯铬酸盐可以将其氧化为1-十三醛[5]它和甲磺酰氯反应,可以得到甲磺酸十三烷基酯。[6]

参考文献

[编辑]
  1. ^ 1.0 1.1 1.2 1.3 1.4 Record in the GESTIS Substance Database from the IFA英语Institute for Occupational Safety and Health
  2. ^ Dénes Szabó, Ana-Maria Bonto, István Kövesdi, Ágnes Gömöry, József Rábai. Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tert-butyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation. Journal of Fluorine Chemistry. 2005-04, 126 (4): 639–650 [2021-11-29]. doi:10.1016/j.jfluchem.2005.01.017. (原始内容存档于2018-06-27) (英语). 
  3. ^ Fuchikami, Takamasa; He, De-Hua; Wakasa, Noriko. Process for producing alcohols by catalytic hydrogenation of carboxylic acids. 1995 WO 9524371 A1.
  4. ^ Dimitris Noutsias, Georgios Vassilikogiannakis. First Total Synthesis of Paracaseolide A. Organic Letters. 2012-07-20, 14 (14): 3565–3567 [2021-11-29]. ISSN 1523-7060. doi:10.1021/ol301481t. (原始内容存档于2021-11-29) (英语). 
  5. ^ Veeresa Gududuru, Kui Zeng, Ryoko Tsukahara, Natalia Makarova, Yuko Fujiwara, Kathryn R. Pigg, Daniel L. Baker, Gabor Tigyi, Duane D. Miller. Identification of Darmstoff analogs as selective agonists and antagonists of lysophosphatidic acid receptors. Bioorganic & Medicinal Chemistry Letters. 2006-01, 16 (2): 451–456 [2021-11-29]. doi:10.1016/j.bmcl.2005.08.096. (原始内容存档于2020-02-21) (英语). 
  6. ^ Christopher McGuigan, Karen Hinsinger, Laura Farleigh, Ranjith N. Pathirana, Joachim J. Bugert. Novel Antiviral Activity of l -Dideoxy Bicyclic Nucleoside Analogues versus Vaccinia and Measles Viruses in Vitro. Journal of Medicinal Chemistry. 2013-02-14, 56 (3): 1311–1322 [2021-11-29]. ISSN 0022-2623. doi:10.1021/jm301778x. (原始内容存档于2021-11-29) (英语).