HKUST-1性质表

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HKUST-1的一些性质如下所述。

基本信息[编辑]

  • 中文名:均苯三甲酸铜(II)
  • 通用名:HKUST-1
  • 化学式:[Cu3(C9H3O6)2(H2O)3]n
  • CAS号:222404-02-6
  • 英文名:Triaqua[μ-[1,3,5-benzenetricarboxylato(3-)-κO1:κO'1]][μ3-[1,3,5-benzenetricarboxylato(3-)-κO1:κO3:κO'1]]tricopper
  • 外观:蓝绿色晶体(三水)或暗蓝色固体(无水)

结构与性质[编辑]

结构与性质
晶体结构 面心立方
空间群 Fm3m[1]
晶胞参数 a=26.2833(2)(100 K)
a=26.2600(3)(356 K)
a=26.2424(4)(500 K)[1]
键长 Cu-Cu:2.628(2) A
Cu-OCO:1.952(3) A
Cu-OH2 = 2.165(8) A[2]
键角
CCDC数据库 链接

谱图性质[编辑]

UV-Vis
λmax
Extinction coefficient
IR
Major absorption bands 参见文献[3]
MS
Ionization potentials from
electron impact
XRD
XRD图谱 参见文献[3][4]

参考文献[编辑]

  1. ^ 1.0 1.1 Yue Wu, Atsushi Kobayashi, Gregory J. Halder, Vanessa K. Peterson, Karena W. Chapman, Nina Lock, Peter D. Southon, Cameron J. Kepert. Negative Thermal Expansion in the Metal-Organic Framework Material Cu3(1,3,5-benzenetricarboxylate)2. Angewandte Chemie International Edition. 2008-11-03, 47 (46): 8929–8932 [2018-04-16]. ISSN 1521-3773. doi:10.1002/anie.200803925 (英语). 
  2. ^ Stephen S.-Y. Chui, Samuel M.-F. Lo, Jonathan P. H. Charmant, A. Guy Orpen, Ian D. Williams. A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n. Science. 1999-02-19, 283 (5405): 1148–1150 [2018-04-16]. ISSN 0036-8075. doi:10.1126/science.283.5405.1148 (英语). 
  3. ^ 3.0 3.1 Zong-Qun Li, Ling-Guang Qiu, Tao Xu, Yun Wu, Wei Wang, Zhen-Yu Wu, Xia Jiang. Ultrasonic synthesis of the microporous metal–organic framework Cu3(BTC)2 at ambient temperature and pressure: An efficient and environmentally friendly method. Materials Letters: 78–80. [2018-04-16]. doi:10.1016/j.matlet.2008.09.010. . Supplement Information for IR data
  4. ^ Miyuki HASHIMOTO, Satoshi OKAJIMA, Toshihiro KONDO, Kenji HARA, Wang-Jae CHUN. Thin Film Structures of Metal-Organic Framework [Cu3(BTC)2(H2O)3]n on TiO2(110). Electrochemistry. 2014-05-05, 82 (5): 335–337 [2018-04-16]. ISSN 1344-3542. doi:10.5796/electrochemistry.82.335 (英语).