N-甲基-N-苄基亚硝胺

N-甲基-N-苄基亚硝胺
别名	甲基苄基亚硝胺
识别
CAS号	937-40-6
PubChem	13643
性质
化学式	C8H10N2O
摩尔质量	150.18 g·mol−1
外观	无色至浅黄色油状液体
溶解性（水）	微溶于氯仿或甲醇
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

N-甲基-N-苄基亚硝胺是一种有机化合物，化学式为C₈H₁₀N₂O，具有急性毒性和致癌性（cat. 1B）^[1]^{[需要更多来源]}。它可由N-甲基苄胺和亚硝酸钠在酸性溶液中反应，或在乙腈/水中进行电化学反应得到。^[2]它在四氯化钛/硼氢化钠体系中可以被还原为N-甲基苄胺。^[3]它可以被过氧化氢氧化为N-甲基-N-硝基苄胺。^[4]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 Safety Data Sheet of N-Nitroso-N-methylbenzylamine （页面存档备份，存于互联网档案馆）. TRC Canada. 2021-10-11
^ Ali, Rojan; Babaahmadi, Rasool; Didsbury, Matthew; Stephens, Rebecca; Melen, Rebecca L.; Wirth, Thomas. Flow Electrochemistry for the N ‐Nitrosation of Secondary Amines. Chemistry – A European Journal. 2023-06-07, 29 (32). ISSN 0947-6539. doi:10.1002/chem.202300957.
^ Kano, Shinzo; Tanaka, Yasuyuki; Sugino, Eiichi; Shibuya, Shiroshi; Hibino, Satoshi. Reductive Denitrosation of Nitrosamines to Secondary Amines with Metal Halide/Sodium Borohydride. Synthesis. 1980, 1980 (09): 741–742. ISSN 0039-7881. doi:10.1055/s-1980-29196.
^ Boyer, Joseph; Pillai, T.; Ramakrishnan, V. Nitrosamines and Nitramines from Tertiary Amines. Synthesis. 1985, 1985 (6/7): 677–679. ISSN 0039-7881. doi:10.1055/s-1985-31307.

[trc-1] 1.0 ^1.1 ^1.2 Safety Data Sheet of N-Nitroso-N-methylbenzylamine （页面存档备份，存于互联网档案馆）. TRC Canada. 2021-10-11

[2] Ali, Rojan; Babaahmadi, Rasool; Didsbury, Matthew; Stephens, Rebecca; Melen, Rebecca L.; Wirth, Thomas. Flow Electrochemistry for the N ‐Nitrosation of Secondary Amines. Chemistry – A European Journal. 2023-06-07, 29 (32). ISSN 0947-6539. doi:10.1002/chem.202300957.

[3] Kano, Shinzo; Tanaka, Yasuyuki; Sugino, Eiichi; Shibuya, Shiroshi; Hibino, Satoshi. Reductive Denitrosation of Nitrosamines to Secondary Amines with Metal Halide/Sodium Borohydride. Synthesis. 1980, 1980 (09): 741–742. ISSN 0039-7881. doi:10.1055/s-1980-29196.

[4] Boyer, Joseph; Pillai, T.; Ramakrishnan, V. Nitrosamines and Nitramines from Tertiary Amines. Synthesis. 1985, 1985 (6/7): 677–679. ISSN 0039-7881. doi:10.1055/s-1985-31307.

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