N-甲基-N-苄基亚硝胺

N-甲基-N-苄基亞硝胺
別名	甲基苄基亞硝胺
識別
CAS號	937-40-6
PubChem	13643
性質
化學式	C8H10N2O
摩爾質量	150.18 g·mol−1
外觀	無色至淺黃色油狀液體
溶解性（水）	微溶於氯仿或甲醇
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

N-甲基-N-苄基亞硝胺是一種有機化合物，化學式為C₈H₁₀N₂O，具有急性毒性和致癌性（cat. 1B）^[1]^{[需要更多來源]}。它可由N-甲基苄胺和亞硝酸鈉在酸性溶液中反應，或在乙腈/水中進行電化學反應得到。^[2]它在四氯化鈦/硼氫化鈉體系中可以被還原為N-甲基苄胺。^[3]它可以被過氧化氫氧化為N-甲基-N-硝基苄胺。^[4]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 Safety Data Sheet of N-Nitroso-N-methylbenzylamine （頁面存檔備份，存於互聯網檔案館）. TRC Canada. 2021-10-11
^ Ali, Rojan; Babaahmadi, Rasool; Didsbury, Matthew; Stephens, Rebecca; Melen, Rebecca L.; Wirth, Thomas. Flow Electrochemistry for the N ‐Nitrosation of Secondary Amines. Chemistry – A European Journal. 2023-06-07, 29 (32). ISSN 0947-6539. doi:10.1002/chem.202300957.
^ Kano, Shinzo; Tanaka, Yasuyuki; Sugino, Eiichi; Shibuya, Shiroshi; Hibino, Satoshi. Reductive Denitrosation of Nitrosamines to Secondary Amines with Metal Halide/Sodium Borohydride. Synthesis. 1980, 1980 (09): 741–742. ISSN 0039-7881. doi:10.1055/s-1980-29196.
^ Boyer, Joseph; Pillai, T.; Ramakrishnan, V. Nitrosamines and Nitramines from Tertiary Amines. Synthesis. 1985, 1985 (6/7): 677–679. ISSN 0039-7881. doi:10.1055/s-1985-31307.

[trc-1] 1.0 ^1.1 ^1.2 Safety Data Sheet of N-Nitroso-N-methylbenzylamine （頁面存檔備份，存於互聯網檔案館）. TRC Canada. 2021-10-11

[2] Ali, Rojan; Babaahmadi, Rasool; Didsbury, Matthew; Stephens, Rebecca; Melen, Rebecca L.; Wirth, Thomas. Flow Electrochemistry for the N ‐Nitrosation of Secondary Amines. Chemistry – A European Journal. 2023-06-07, 29 (32). ISSN 0947-6539. doi:10.1002/chem.202300957.

[3] Kano, Shinzo; Tanaka, Yasuyuki; Sugino, Eiichi; Shibuya, Shiroshi; Hibino, Satoshi. Reductive Denitrosation of Nitrosamines to Secondary Amines with Metal Halide/Sodium Borohydride. Synthesis. 1980, 1980 (09): 741–742. ISSN 0039-7881. doi:10.1055/s-1980-29196.

[4] Boyer, Joseph; Pillai, T.; Ramakrishnan, V. Nitrosamines and Nitramines from Tertiary Amines. Synthesis. 1985, 1985 (6/7): 677–679. ISSN 0039-7881. doi:10.1055/s-1985-31307.

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