4-氯乙苯
| 4-氯乙苯 | |
|---|---|
| |
| 識別 | |
| CAS號 | 622-98-0 
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| SMILES |
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| 性質 | |
| 化學式 | C8H9Cl |
| 摩爾質量 | 140.61 g·mol−1 |
| 沸點 | 185 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
4-氯乙苯是一種有機氯化合物，化學式為C8H9Cl。它可由乙苯和次氯酸叔丁酯在沸石存在下於乙腈中反應製得，該反應會產生少量的2-氯乙苯。[2]
反應
[編輯]4-氯乙苯和過氧化叔丁醇在氯化銅、新銅試劑的催化下反應，可以得到4'-氯苯乙酮。[3]
參考文獻
[編輯]- ^ Ignacio Aracil, Rafael Font, and Juan A. Conesa. Chlorinated and Nonchlorinated Compounds from the Pyrolysis and Combustion of Polychloroprene. Environ. Sci. Technol. 2010, 44, 11, 4169–4175. doi:10.1021/es100023a. S.I. pp S4.
- ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
- ^ Md. Munkir Hossain, Shin-Guang Shyu. Biphasic copper-catalyzed C–H bond activation of arylalkanes to ketones with tert-butyl hydroperoxide in water at room temperature. Tetrahedron. 2016. 72 (29). doi:10.1016/j.tet.2016.05.066.