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4-氯乙苯

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4-氯乙苯
識別
CAS號 622-98-0  checkY
SMILES
 
  • ClC1=CC=C(C=C1)CC
性質
化學式 C8H9Cl
摩爾質量 140.61 g·mol−1
沸點 185 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

4-氯乙苯是一種有機氯化合物,化學式為C8H9Cl。它可由乙苯次氯酸叔丁酯沸石存在下於乙腈中反應製得,該反應會產生少量的2-氯乙苯[2]

反應

[編輯]

4-氯乙苯和過氧化叔丁醇氯化銅新銅試劑的催化下反應,可以得到4'-氯苯乙酮維基數據所列Q27295903[3]

參考文獻

[編輯]
  1. ^ Ignacio Aracil, Rafael Font, and Juan A. Conesa. Chlorinated and Nonchlorinated Compounds from the Pyrolysis and Combustion of Polychloroprene. Environ. Sci. Technol. 2010, 44, 11, 4169–4175. doi:10.1021/es100023a. S.I. pp S4.
  2. ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
  3. ^ Md. Munkir Hossain, Shin-Guang Shyu. Biphasic copper-catalyzed C–H bond activation of arylalkanes to ketones with tert-butyl hydroperoxide in water at room temperature. Tetrahedron. 2016. 72 (29). doi:10.1016/j.tet.2016.05.066.