缩酚酸
外观
![](http://upload.wikimedia.org/wikipedia/commons/thumb/3/39/Depside.svg/180px-Depside.svg.png)
![](http://upload.wikimedia.org/wikipedia/commons/thumb/a/a1/Gyrophoric_acid.svg/170px-Gyrophoric_acid.svg.png)
![](http://upload.wikimedia.org/wikipedia/commons/thumb/3/3d/Salsalate.svg/170px-Salsalate.svg.png)
缩酚酸(英语:Depside)是一类多酚化合物,由两个或多个酚酸通过酯键形成,存在于许多维管植物中[1],如杜鹃花科[2]、唇形科[3]、罂粟科[4]、桃金娘科[5]等,同时许多地衣中的共生真菌也会产生缩酚酸[6][7]。
例子
[编辑]二缩酚酸
[编辑]化合物 | 分子式 | 结构 | 酚酸单元 | CAS号 |
---|---|---|---|---|
双水杨酯 Salsalate |
C14H10O5 | ![]() |
水杨酸-2-水杨酸酯 | 552-94-3 |
二没食子酸 Digallic acid |
C14H10O9 | ![]() |
没食子酸-3-没食子酸酯 | 536-08-3 |
对双没食子酸 | C14H10O9 | 没食子酸-4-没食子酸酯 | 47307-06-2 | |
红粉苔酸 Lecanoric acid |
C16H14O7 | ![]() |
苔色酸-4-苔色酸酯 | 480-56-8 |
异红粉苔酸 Isolecanoric acid |
C16H14O7 | ![]() |
苔色酸-2-苔色酸酯 | 110064-65-8 |
绵腹衣酸 Anziaic acid |
C24H30O7 | ![]() |
橄榄酸-4-橄榄酸酯 | 641-68-9 |
化合物 | 分子式 | 结构 | 酚酸单元 | CAS号 |
---|---|---|---|---|
2-原儿茶酰间苯三酚羧酸 2-Protocatechuoyl phloroglucinolcarboxylate |
C14H10O8 | 间苯三酚羧酸-2-原儿茶酸酯 | 30048-34-1 | |
扁枝衣二酸 Evernic acid |
C17H16O7 | ![]() |
?—苔色酸酯 | 537-09-7 |
拉马酸 Ramalic acid |
C18H18O7 | ![]() |
?—苔色酸酯 | 500-37-8 |
黑茶渍素 Atranorin |
C19H18O8 | ![]() |
479-20-9 | |
地弗地衣酸 Diffractaic acid |
C20H22O7 | ![]() |
436-32-8 | |
石花酸 Sekikaic acid |
C22H26O8 | ![]() |
607-11-4 | |
高石花酸 Homosekikaic acid |
C24H30O8 | 486-36-2 | ||
Merochlorophaeic acid Merochlorophaeic acid |
C24H30O8 | ![]() |
2879-80-3 | |
珠光酸 perlatolic acid |
C25H32O7 | ![]() |
?—橄榄酸酯 | 529-47-5 |
三缩酚酸
[编辑]化合物 | 分子式 | 结构 | CAS号 |
---|---|---|---|
三苔色酸 Gyrophoric acid |
C24H20O10 | ![]() |
548-89-0 |
石耳酸 Umbilicaric acid |
C25H20O10 | ![]() |
30666-92-3 |
海亚丝酸 Hiascic acid |
C24H20O11 | ![]() |
537-07-5 |
衍生物
[编辑]参考文献
[编辑]- ^ 1.0 1.1 刘冰倩,王晶晶,贾妍,等. 松萝属地衣化学成分及生物活性研究进展. 中草药. 2020, 51 (13): 3584–3594. doi:10.7501/j.issn.0253-2670.2020.13.029.
- ^ Ono M, Masuoka C, Koto M, Tateishi M, Komatsu H, Kobayashi H, Igoshi K, Ito Y, Okawa M, Nohara T. Antioxidant ortho-benzoyloxyphenyl acetic acid ester, vaccihein A, from the fruit of rabbiteye blueberry (Vaccinium ashei). Chem. Pharm. Bull. October 2002, 50 (10): 1416–7. PMID 12372879. doi:10.1248/cpb.50.1416
.
- ^ Zgórka G, Głowniak K. Variation of free phenolic acids in medicinal plants belonging to the Lamiaceae family. J Pharm Biomed Anal. August 2001, 26 (1): 79–87. PMID 11451645. doi:10.1016/S0731-7085(01)00354-5.
- ^ Hillenbrand M, Zapp J, Becker H. Depsides from the petals of Papaver rhoeas. Planta Med. April 2004, 70 (4): 380–2. PMID 15095160. doi:10.1055/s-2004-818956.
- ^ Reynertson KA, Wallace AM, Adachi S, Gil RR, Yang H, Basile MJ, D'Armiento J, Weinstein IB, Kennelly EJ. Bioactive depsides and anthocyanins from jaboticaba (Myrciaria cauliflora). J. Nat. Prod. August 2006, 69 (8): 1228–30. PMID 16933884. doi:10.1021/np0600999.
- ^ Daniele Armaleo, Yi Zhang, Sonia Cheung. Light might regulate divergently depside and depsidone accumulation in the lichen Parmotrema hypotropum by affecting thallus temperature and water potential. Mycologia. 2008, 100 (4): 565-576. doi:10.3852/07-162R.
- ^ Nobuo Hamada. The effect of various culture conditions on depside production by an isolated lichen mycobiont. The Bryologist. 1989, 92 (3): 310-313. doi:10.2307/3243399.