丁二硫醚

丁二硫醚
别名	二丁基二硫; 二正丁基二硫; 二正丁基二硫醚
识别
CAS号	629-45-8
性质
化学式	C8H18S2
摩尔质量	178.36 g·mol⁻¹
密度	0.930 g·cm−3（20 °C）
熔点	116—118 °C（389—391 K）
沸点	228—230 °C（501—503 K）
相关物质
相关化学品	丁硫醚（日语：ジブチルスルフィド）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

丁二硫醚或二丁基二硫是一种有机化合物，化学式为C₈H₁₈S₂。它可由正丁硫醇的氧化反应制得。^[4]它在二氯甲烷中可以被间氯过氧苯甲酸氧化，生成丁基硫代亚磺酸-S-丁酯。^[5]它和溴化苄、锌在三氯化铝催化下反应，可以得到苄基丁硫醚。^[6]

参考文献[编辑]

^ Gilman, Henry; Smith, Lloyd E.; Parker, Harold H. THE CONSTITUTION OF DISULFOXIDES. Journal of the American Chemical Society (American Chemical Society (ACS)). 1925, 47 (3): 851–860. ISSN 0002-7863. doi:10.1021/ja01680a037.
^ Habib Firouzabadi, Daryoush Mohajer, Mohsen Entezari-Moghadam. Barium Ferrate Monohydrate BaFeO 4 ·H 2 O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions. Bulletin of the Chemical Society of Japan. 1988-06, 61 (6): 2185–2189 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.61.2185. （原始内容存档于2021-12-02）（英语）.
^ Hisashi Fujihara, Ryouichi Akaishi, Naomichi Furukawa. A Mild, High-Yield Conversion of Thiols into Disulfides Using Disulfide Dication Salt: A New Redox System. Bulletin of the Chemical Society of Japan. 1989-02, 62 (2): 616–617 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.62.616. （原始内容存档于2021-12-02）（英语）.
^ Abhinandan D. Hudwekar, Praveen K. Verma, Jaspreet Kour, Shilpi Balgotra, Sanghapal D. Sawant. Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides: Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazole. European Journal of Organic Chemistry. 2019-02-14, 2019 (6): 1242–1250 [2021-12-10]. doi:10.1002/ejoc.201801610 （英语）.
^ Jinyue Su, Yatao Qiu, Kun Ma, Yiwu Yao, Zhen Wang, Xianling Li, Dayong Zhang, Zhengchao Tu, Sheng Jiang. Design, synthesis, and biological evaluation of largazole derivatives: alteration of the zinc-binding domain. Tetrahedron. 2014-10, 70 (42): 7763–7769 [2021-12-10]. doi:10.1016/j.tet.2014.05.078. （原始内容存档于2018-07-01）（英语）.
^ M. M. Lakouraj, B. Movassagh, Z. Fadaei. SYNTHESIS OF ORGANIC SULFIDES VIA Zn/AlCl 3 SYSTEM IN AQUEOUS MEDIA. Synthetic Communications. 2002-01, 32 (8): 1237–1242 [2021-12-10]. ISSN 0039-7911. doi:10.1081/SCC-120003615 （英语）.

[1] Gilman, Henry; Smith, Lloyd E.; Parker, Harold H. THE CONSTITUTION OF DISULFOXIDES. Journal of the American Chemical Society (American Chemical Society (ACS)). 1925, 47 (3): 851–860. ISSN 0002-7863. doi:10.1021/ja01680a037.

[2] Habib Firouzabadi, Daryoush Mohajer, Mohsen Entezari-Moghadam. Barium Ferrate Monohydrate BaFeO 4 ·H 2 O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions. Bulletin of the Chemical Society of Japan. 1988-06, 61 (6): 2185–2189 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.61.2185. （原始内容存档于2021-12-02）（英语）.

[3] Hisashi Fujihara, Ryouichi Akaishi, Naomichi Furukawa. A Mild, High-Yield Conversion of Thiols into Disulfides Using Disulfide Dication Salt: A New Redox System. Bulletin of the Chemical Society of Japan. 1989-02, 62 (2): 616–617 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.62.616. （原始内容存档于2021-12-02）（英语）.

[4] Abhinandan D. Hudwekar, Praveen K. Verma, Jaspreet Kour, Shilpi Balgotra, Sanghapal D. Sawant. Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides: Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazole. European Journal of Organic Chemistry. 2019-02-14, 2019 (6): 1242–1250 [2021-12-10]. doi:10.1002/ejoc.201801610 （英语）.

[5] Jinyue Su, Yatao Qiu, Kun Ma, Yiwu Yao, Zhen Wang, Xianling Li, Dayong Zhang, Zhengchao Tu, Sheng Jiang. Design, synthesis, and biological evaluation of largazole derivatives: alteration of the zinc-binding domain. Tetrahedron. 2014-10, 70 (42): 7763–7769 [2021-12-10]. doi:10.1016/j.tet.2014.05.078. （原始内容存档于2018-07-01）（英语）.

[6] M. M. Lakouraj, B. Movassagh, Z. Fadaei. SYNTHESIS OF ORGANIC SULFIDES VIA Zn/AlCl 3 SYSTEM IN AQUEOUS MEDIA. Synthetic Communications. 2002-01, 32 (8): 1237–1242 [2021-12-10]. ISSN 0039-7911. doi:10.1081/SCC-120003615 （英语）.

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