二苯基溴甲烷

二苯基溴甲烷
	IUPAC名; 1,1′-(Bromomethylene)dibenzene
别名	α-苯基苄溴; α-溴二苯甲烷
识别
CAS号	776-74-9
PubChem	236603
ChemSpider	206530
SMILES	BrC(c1ccccc1)c2ccccc2;
InChI	InChI=1S/C13H11Br/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H;
性质
化学式	C13H11Br
摩尔质量	247.13 g·mol−1
熔点	45 °C（318 K）
沸点	178 °C（17 torr）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二苯基溴甲烷是一种有机化合物，化学式为C₁₃H₁₁Br。它可由二苯甲醇的溴化反应制得。^[3]它和叠氮化钠在二甲基亚砜中反应，可以得到二苯基叠氮甲烷。^[4]它和甲苯在三氟化硼乙醚存在下反应，可以得到4-甲基三苯甲烷，副产物2-甲基三苯甲烷。^[5]

参考文献[编辑]

^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-3-9].
^ Margolis, D. S.; Pittman, R. W. Products of the interaction of hydrogen selenide and ketones. Journal of the Chemical Society, 1957: 799-805.
^ Nilesh R Tawari, Seema Bag, Archana Raju, Arundhati C Lele, Ranjeet Bairwa, Mukti Kanta Ray, Mgr Rajan, Laxman U Nawale, Dhiman Sarkar, Mariam S Degani. Rational drug design, synthesis and biological evaluation of dihydrofolate reductase inhibitors as antituberculosis agents. Future Medicinal Chemistry. 2015-06, 7 (8): 979–988 [2022-03-09]. ISSN 1756-8919. doi:10.4155/fmc.15.48 （英语）.
^ Christophe Pardin, Isabelle Roy, William D. Lubell, Jeffrey W. Keillor. Reversible and Competitive Cinnamoyl Triazole Inhibitors of Tissue Transglutaminase. Chemical Biology & Drug Design. 2008-09, 72 (3): 189–196 [2022-03-09]. doi:10.1111/j.1747-0285.2008.00696.x. （原始内容存档于2022-03-09）（英语）. （页面存档备份，存于互联网档案馆）
^ Ruofeng Huang, Xiaohui Zhang, Jing Pan, Jiaqiang Li, Hang Shen, Xuege Ling, Yan Xiong. Benzylation of arenes with benzyl halides synergistically promoted by in situ generated superacid boron trifluoride monohydrate and tetrahaloboric acid. Tetrahedron. 2015-03, 71 (10): 1540–1546 [2022-03-09]. doi:10.1016/j.tet.2015.01.037. （原始内容存档于2020-03-02）（英语）. （页面存档备份，存于互联网档案馆）