七磷化三銣
| 七磷化三銣 | |
|---|---|
| 識別 | |
| CAS號 | 86096-79-9 
|
| 性質 | |
| 化學式 | P7Rb3 |
| 摩爾質量 | 473.22 g·mol−1 |
| 外觀 | 黃色晶體（七氨合物）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
七磷化三銣是一種無機化合物，化學式為Rb3P7，它由籠狀的P73−陰離子和Rb+構成。[2]它可由銣和紅磷按化學計量比在高溫反應製得。[3]它和四甲基碘化銨在液氨中反應，可以得到[(CH3)4N]2RbP7(NH3)。[4]
參考文獻
[編輯]- ^ Kraus, Florian; Korber, Nikolaus. The chemical bond in polyphosphides: Crystal structures, the electron localization function, and a new view of aromaticity in P42- and P5-. Chemistry - A European Journal (2005), 11 (20), 5945-5959. doi:10.1002/chem.200500414.
- ^ Bolduan, F.; Hoenle, W.; Hochheimer, H. D.; Henkel, W. Temperature and High Pressure Raman Study of M3P7 (M = Li, Na, K, Rb, Cs) Compounds. Physica Status Solidi B: Basic Research (1985), 132(1), 41-50. doi:10.1002/pssb.2221320103.
- ^ K. Tentschev; E. Gmelin; W. Hönle (1985). Phase transitions crystalline to plastic-crystalline and the specific heat of M3P7 compounds (M = Li, Na, K, Rb, Cs). Thermochimica Acta, 85, 151–154. doi:10.1016/0040-6031(85)85552-0
- ^ Korber, Nikolaus; von Schnering, Hans Georg. Alkali metal polyphosphides in low dimensions. Preparation and structure of [Me4N]2RbP7(NH3) and [Et4N]Cs2P11. Chemische Berichte (1996), 129(2), 155-159. doi:10.1002/cber.19961290208