二十四碳化鉀

二十四碳化鉀是一種石墨插層化合物，化學式為KC₂₄。它可由八碳化鉀和石墨在350~450 °C共熱反應製得，^[2]或由鉀和石墨在真空中於350 °C反應得到。^[1]它在Co(C₂H₄)(PMe₃)₃催化下和鋰在戊烷中反應，可以得到Li_2.67KC₂₄。^[3]

參考文獻[編輯]

^ ^1.0 ^1.1 Ichikawa, Masaru; Inoue, Yukio; Tamaru, Kenzi. Catalytic hydrogenation of benzene by graphite-potassium lamellar compounds C8K and C24K. Journal of the Chemical Society, Chemical Communications (1972), (16), 928-929. doi:10.1039/C39720000928.
^ Akuzawa, Noboru; Kunihashi, Yoji; Sato, Yuki; Tsuchiya, Ken-ichi; Matsumoto, Rika. Effect of sorbed molecules on the resistivity of alkali metal-graphite intercalation compounds. Journal of Solid State Chemistry (2007), 180(3), 894-901. doi:10.1016/j.jssc.2006.12.019.
^ Klein, H. F.; Dreisbach, M.; Gass, M.; Cordier, G. Saturation intercalation - preparation of first stacked lithium/potassium graphitides. Materials Science Forum (1992), 91-93: 35-40. doi:10.4028/www.scientific.net/MSF.91-93.35.

Shioyama, Hiroshi. The reaction of potassium-graphite intercalation compounds with halogens（日語）. Tanso, 2002. 203. 120-122. ISSN 0371-5345.