氮化锌：修订间差异
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2014年7月12日 (六) 14:54的版本
| Zinc nitride | |
|---|---|
| |
| 识别 | |
| CAS号 | 1313-49-1 
|
| 性质 | |
| 化学式 | Zn3N2 |
| 摩尔质量 | 224.15 g/mol[1] g·mol⁻¹ |
| 外观 | 灰色粉末[1] |
| 密度 | 6.22 g/cm³（固体）[1] |
| 溶解性（水） | 不溶(分解) |
| 结构 | |
| 晶体结构 | 立方晶系, cI80 |
| 空间群 | Ia-3, No. 206[1][2] |
| 危险性 | |
| 欧盟分类 | 未列出 |
| NFPA 704 |
 0
1
1
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| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氮化锌是一种无机化合物，化学式为Zn3N2。纯的氮化锌的结构属于立方晶系。[1][2]
制备
氮化锌可以通过氨基锌的在无氧环境中的热分解（200℃）得到，[3]此反应的副产品是氨气。[4]
氮化锌也可以在600℃用锌和氨反应得到，反应会产生氢气：[3][5]
化学性质
Zinc nitride reacts violently with water to form ammonia and zinc oxide.[3][4]
氮化锌可溶于盐酸。[6] and "reversibly reacts with lithium electrochemically".[7] Like magnesium nitride (Mg3N2) and lithium nitride (Li3N), it has a high melting point.[8]
参考资料
- ^ 1.0 1.1 1.2 1.3 1.4 Sangeeta, D. Inorganic Materials Chemistry Desk Reference. CRC Press. 1997: 278 [2007-09-30]. ISBN 978-0-8493-8900-9.
- ^ 2.0 2.1 Partin, D. E.; Williams, D. J.; O'Keeffe, M. The Crystal Structures of Mg3N2 and Zn3N2. Journal of Solid State Chemistry. 1997, 132 (1): 56–59. Bibcode:1997JSSCh.132...56P. doi:10.1006/jssc.1997.7407.
- ^ 3.0 3.1 3.2 Roscoe, H. E.; Schorlemmer, C. A Treatise on Chemistry: Volume II, The Metals 4th. London: Macmillan. 1907: 650–651 [1878] [2007-11-01].
- ^ 4.0 4.1 Bloxam, C. L. Chemistry, Inorganic and Organic 9th. Philadelphia: P. Blakiston's Son & Co. 1903: 380 [2007-10-31].
- ^ Lowry, M. T. Inorganic Chemistry. Macmillan. 1922: 872 [2007-11-01].
- ^ Comey, A. M.; Hahn, D. A. A Dictionary of Chemical Solubilities: Inorganic 2nd. New York: Macmillan. 1921: 1124 [2007-11-01].
- ^ Amatucci, G. G.; Pereira, N. Nitride and Silicide Negative Electrodes. Nazri, G.-A.; Pistoia, G. (编). Lithium Batteries: Science and Technology. Kluwer Academic Publishers. 2004: 256 [2007-11-01]. ISBN 978-1-4020-7628-2.
- ^ Grolier Incorporated. Academic American Encyclopedia. Danbury, CT: Grolier Inc. 1994: 202 [2007-11-01]. ISBN 978-0-7172-2053-3.
扩展阅读
- Futsuhara, M.; Yoshioka, K.; Takai, O. Structural, electrical and optical properties of zinc nitride thin films prepared by reactive RF magnetron sputtering. Thin Solid Films (Elsevier). 1998, 322 (1): 274–281. Bibcode:1998TSF...322..274F. doi:10.1016/S0040-6090(97)00910-3.
- Lyutaya, M. D.; Bakuta, S. A. Synthesis of the nitrides of Group II elements. Powder Metallurgy and Metal Ceramics (Springer). 1980, 19 (2): 118–122. doi:10.1007/BF00792038.
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