碱式乙酸铬 是一种配位化合物 ,化学式为[Cr3 O(OAc)6 (H2 O)3 ]OAc (OAc为CH3 CO2 − )。它可由氯化铬 六水合物和氢氧化钠 于水中反应,其沉淀再和无水乙酸 反应制得;若和氘代乙酸反应,则得到[Cr3 O(O2 CD3 )6 (H2 O)3 ](O2 CCD3 )。[ 1] 它在DMF 中和苯甲酸 煮沸后,再和高氯酸 反应,可以得到[Cr3 O(OPh)6 (H2 O)3 ]ClO4 ·solv 。[ 2] 它和硅钼酸钾 在pH 2下反应,可以得到KH2 [Cr3 O(O2 CCH3 )6 (H2 O)3 ][SiMo12 O40 ]·11H2 O,钨类似物 可通过相似方法反应得到。[ 3]
^ David M. Low, Gopalan Rajaraman, Madeleine Helliwell, Grigore Timco, Joris van Slageren, Roberta Sessoli, Stefan T. Ochsenbein, Roland Bircher, Christopher Dobe, Oliver Waldmann, Hans-Ulrich Güdel, Mark A. Adams, Eliseo Ruiz, Santiago Alvarez, Eric J. L. McInnes. A Family of Ferro- and Antiferromagnetically Coupled Decametallic Chromium(III) Wheels . Chemistry - A European Journal. 2006-02-01, 12 (5): 1385–1396 [2023-03-21 ] . ISSN 0947-6539 . doi:10.1002/chem.200501041 (英语) .
^ Batsanov, A. S.; Struchkov, Yu. T.; Gerbeleu, N. V.; Timko, G. A.; Manole, O. S. Synthesis and crystal structure of (μ3-oxo)hexa(benzoato)triaquatrichromium(III) perchlorate. Koordinatsionnaya Khimiya , 1994. 20 (11): 833-837.
^ Xiaoshu Qu, Lin Xu, Yunfeng Qiu, Guanggang Gao, Fengyan Li, Yanyan Yang. New Series of Porous Ionic Crystals Constructed from Various Polyoxometalate Anions and Macrocations: Syntheses, Crystal Structures, and Comparison with Diverse Spatial Arrangement . Zeitschrift für anorganische und allgemeine Chemie. 2007-06, 633 (7): 1040–1047 [2023-03-21 ] . doi:10.1002/zaac.200600330 . (原始内容存档 于2023-03-21) (德语) .