碱式乙酸锌
外观
碱式乙酸锌 | |
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识别 | |
CAS号 | 12129-82-7 ![]() |
性质 | |
化学式 | C12H18O13Zn4 |
摩尔质量 | 631.9 g·mol−1 |
外观 | 晶体 |
密度 | 1.903 g·cm−3[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
碱式乙酸锌是一种乙酸盐,化学式为Zn4O(CH3COO)6,它和碱式乙酸铍同构。它可以催化苯胺的烷氧基羰基化反应。[2]
制备与反应
[编辑]它可由乙酸锌在真空中热分解,升华得到;[1]或通过氧化锌和乙酸按一定比例反应制得。[3]
它和对苯二甲酸在DEF中于100 °C反应,可以得到MOF-5(Zn)。[4]
参考文献
[编辑]- ^ 1.0 1.1 Hirozo Koyama, Yoshihiko Saito. The Crystal Structure of Zinc Oxyacetate, Zn 4 O(CH 3 COO) 6. Bulletin of the Chemical Society of Japan. 1954-02, 27 (2): 112–114 [2023-03-21]. ISSN 0009-2673. doi:10.1246/bcsj.27.112. (原始内容存档于2023-03-21) (英语).
- ^ Elisenda Reixach, Robert M. Haak, Stefan Wershofen, Anton Vidal-Ferran. Alkoxycarbonylation of Industrially Relevant Anilines Using Zn 4 O(O 2 CCH 3 ) 6 as Catalyst. Industrial & Engineering Chemistry Research. 2012-12-19, 51 (50): 16165–16170 [2023-03-21]. ISSN 0888-5885. doi:10.1021/ie301315k. (原始内容存档于2023-03-21) (英语).
- ^ Rhianydd M. Gordon, Howard B. Silver. Preparation and properties of tetrazinc μ 4 -oxohexa-μ-carboxylates (basic zinc carboxylates). Canadian Journal of Chemistry. 1983-06-01, 61 (6): 1218–1221 [2023-03-21]. ISSN 0008-4042. doi:10.1139/v83-217 (英语).
- ^ Steffen Hausdorf, Felix Baitalow, Tony Böhle, David Rafaja, Florian O. R. L. Mertens. Main-Group and Transition-Element IRMOF Homologues. Journal of the American Chemical Society. 2010-08-18, 132 (32): 10978–10981 [2023-03-21]. ISSN 0002-7863. doi:10.1021/ja1028777. (原始内容存档于2023-03-21) (英语).
拓展阅读
[编辑]- Souad Boulmaâz, Renée Papiernik, Liliane G. Hubert-pfalzgraf, Bernard Septe, Jacqueline Vaissermann. Chemical routes to oxides: alkoxidevs. alkoxide–acetate routes: synthesis, characterization, reactivity and polycondensation of MNb2(OAc)2(OPri)10(M=Mg, Cd, Pb) species. Journal of Materials Chemistry. 1997, 7 (10): 2053–2061 [2023-03-21]. doi:10.1039/a701381g.
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