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乙酸氯

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乙酸氯
别名 次氯酸乙酰酯
识别
CAS号 758-11-2  checkY
SMILES
 
  • ClOC(=O)C
性质
化学式 C2H3ClO2
摩尔质量 94.5 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

乙酸氯是一种化合物,化学式为CH3COOCl,可由氯气的乙酸溶液和干燥的乙酸汞反应得到。[1]它可用于在有机化合物中引入乙酸酯基(CH3C(=O)O-),[2]如和2-氯-4-甲基苯甲醇反应,得到乙酸(2-氯-4-甲基苯基)甲酯[3];和环己烯反应,得到乙酸-2-氯环己酯[4]

参考文献

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  1. ^ De la Mare, P. B. D.; Ketley, A. D.; Vernon, C. A. Chlorine acetate as a reagent for electrophilic chlorine substitution. Research (London), 1953. 6: 12-13S. CAN48: 18058.
  2. ^ Patrycja Miszczyk, Ilona Turowska-Tyrk, Paweł Kafarski, Ewa Chmielewska. Three-Component Reaction of Benzylamines, Diethyl Phosphite and Triethyl Orthoformate: Dependence of the Reaction Course on the Structural Features of the Substrates and Reaction Conditions. Molecules. 2017-03-11, 22 (3): 450 [2020-04-19]. ISSN 1420-3049. PMC 6155184可免费查阅. PMID 28287472. doi:10.3390/molecules22030450. (原始内容存档于2020-02-23) (英语). 
  3. ^ Alemparte-Gallardo, Carlos; Barfoot, Christopher; Barros-Aguirre, David; Cacho-Izquierdo, Monica; Fiandor Roman, Jose Maria; Hennessy, Alan Joseph; Pearson, Neil David; Remuinan-Blanco, Modesto Jesus. Preparation of tricyclic nitrogen containing compounds as antibacterials. 2009. WO 2009141398 A1.
  4. ^ P. B. D. de la Mare, Charmian J. O'Connor, M. J. Rosser, M. A. Wilson. Cyclic transition states in cis- and trans-addition of chlorine acetate to olefinic substances. Journal of the Chemical Society D: Chemical Communications. 1970, (12): 731 [2020-04-19]. ISSN 0577-6171. doi:10.1039/c29700000731 (英语).