乙酸碘(I)是一种碘化试剂,化学式为C2H3IO2,或简写为IOAc。乙酸银和碘在乙醚中反应、乙酸汞和碘在乙酸中反应,或者四乙酸铅和碘在环己烷中反应,均可制得乙酸碘(I)。[1]它可以用于有机化合物的碘化,如可以通过碘和乙酸汞原位产生乙酸碘(I),与五甲基苯反应,得到五甲基碘苯。[2]乙酸碘(I)亦可碘化B–H键。[3]
- ^ Ramesh Giri, Jin-Quan Yu. Iodine Monoacetate. John Wiley & Sons, Ltd. 2008-09-15 [2020-04-19]. ISBN 9780471936237. doi:10.1002/047084289x.rn00915 (英语).
- ^ E. M. Chen, R. M. Keefer, L. J. Andrews. Acetyl Hypoiodite as an Aromatic Iodinating Agent. Journal of the American Chemical Society. 1967-01, 89 (2): 428–430 [2020-04-19]. ISSN 0002-7863. doi:10.1021/ja00978a046 (英语).
- ^ Hairong Lyu, Yangjian Quan, Zuowei Xie. Transition Metal Catalyzed, Regioselective B (4)-Halogenation and B (4,5)-Diiodination of Cage B−H Bonds in o -Carboranes. Chemistry - A European Journal. 2017-10-20, 23 (59): 14866–14871 [2020-04-19]. doi:10.1002/chem.201703006 (英语).