苯並［c］菲

苯並[c]菲（英語：Benzo(c)phenanthrene，也称为[4]螺烯，四螺苯）是一种螺烯类多环芳烃，化学式C₁₈H₁₂。性状为白色固体，溶于非极性有机溶剂。它是非平面分子，两端的苯环组成的二面角为26°^[3]，因而具有轴手性，因此该化合物在理论研究上引起化学家的兴趣。

苯並[c]菲存在于自然界^[4]，是一种弱致癌物质。^[5]

参考资料[编辑]

^ ^1.0 ^1.1 Harvey, Ronald G. Polycyclic aromatic hydrocarbons : chemistry and carcinogenicity. Cambridge: Cambridge University Press. 1991. ISBN 0-521-36458-2. OCLC 22909612.
^ 来源：Sigma-Aldrich Co., product no. BCR134 .
^ Levy, M.; Newman, Melvin S.; Szwarc, M. Methyl Affinities of Non-planar Aromatic Hydrocarbons. Journal of the American Chemical Society. 1955-08, 77 (16): 4225–4225. doi:10.1021/ja01621a015.
^ Tolosa, Imma; de Mora, Stephen; Sheikholeslami, Mohammad Reza; Villeneuve, Jean-Pierre; Bartocci, Jean; Cattini, Chantal. Aliphatic and aromatic hydrocarbons in coastal caspian Sea sediments. Marine Pollution Bulletin. 2004-01-01, 48 (1–2): 44–60. PMID 14725875. doi:10.1016/S0025-326X(03)00255-8.
^ Hirshfeld, F. L.; Sandler, Selina; Schmidt, G. M. J. 398. The structure of overcrowded aromatic compounds. Part VI. The crystal structure of benzo[c]phenanthrene and of 1,12-dimethylbenzo[c]phenanthrene. Journal of the Chemical Society (Resumed). 1963: 2108. doi:10.1039/JR9630002108.