三硫化二铑

三硫化二铑
	IUPAC名; Rhodium(III) sulfide
别名	硫化铑(III)
识别
CAS号	12067-06-0
PubChem	54672740
ChemSpider	23349348
SMILES	S=[Rh]S[Rh]=S;
InChI	1S/2Rh.3S;
EINECS	235-075-0
性质
化学式	Rh2S3
摩尔质量	302.01 g·mol−1
外观	黑色固体
密度	6.46 g/cm−3
溶解性（水）	难溶
结构
晶体结构	正交晶系，Pbcn
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三硫化二铑是一种无机化合物，化学式为Rh₂S₃。它可由铑和硫在高温反应制得；^[2]也可由十六羰基六铑和硫粉在水^[3]或二甲苯^[4]中的溶剂热反应制得。

它是一些化合物的晶体结构原型^[5]，属于Rh₂S₃结构的化合物有Rh₂Se₃、Ir₂S₃、^[2]高压相Sn₂N₂O^[6]等。

参考文献[编辑]

^ Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Shin-ichiro Ono, Kunihisa Terai, Akihiko Nakatsuka, Kazumasa Sugiyama. Single-crystal structure refinements and Debye temperatures of Ir 2 S 3 kashinite and Rh 2 S 3 bowieite. Acta Crystallographica Section C Structural Chemistry. 2022-11-01, 78 (11): 606–611 [2023-03-28]. ISSN 2053-2296. doi:10.1107/S2053229622009603. （原始内容存档于2023-03-28）.
^ ^2.0 ^2.1 E. Parthé, E. Hohnke, F. Hulliger. A new structure type with octahedron pairs for Rh 2 S 3 , Rh 2 Se 3 and Ir 2 S 3. Acta Crystallographica. 1967-11-01, 23 (5): 832–840 [2023-03-28]. ISSN 0365-110X. doi:10.1107/S0365110X67003767. （原始内容存档于2022-12-01）.
^ Wuxing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Phase Controllable Synthesis of Well-Crystallized Rhodium Sulfides by the Hydrothermal Method. Crystal Growth & Design. 2009-08-05, 9 (8): 3765–3770 [2023-03-28]. ISSN 1528-7483. doi:10.1021/cg900454g. （原始内容存档于2023-03-28）（英语）.
^ Wu-xing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Solvothermal Preparation and Control of Phase Composition of Nanosized Rhodium Sulfide Particles. Chemistry Letters. 2009-03-05, 38 (3): 210–211 [2023-03-28]. ISSN 0366-7022. doi:10.1246/cl.2009.210 （英语）.
^ Rh2S3 Structure: A2B3_oP20_60_d_cd. Encyclopedia of Crystallographic Prototypes. [2023-03-28]. （原始内容存档于2023-03-28）.
^ Shrikant Bhat, Leonore Wiehl, Shariq Haseen, Peter Kroll, Konstantin Glazyrin, Philipp Gollé‐Leidreiter, Ute Kolb, Robert Farla, Jo‐Chi Tseng, Emanuel Ionescu, Tomoo Katsura, Ralf Riedel. A Novel High‐Pressure Tin Oxynitride Sn 2 N 2 O. Chemistry – A European Journal. 2020-02-17, 26 (10): 2187–2194 [2023-03-28]. ISSN 0947-6539. PMC 7065226 . PMID 31671223. doi:10.1002/chem.201904529 （英语）.

[1] Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Shin-ichiro Ono, Kunihisa Terai, Akihiko Nakatsuka, Kazumasa Sugiyama. Single-crystal structure refinements and Debye temperatures of Ir 2 S 3 kashinite and Rh 2 S 3 bowieite. Acta Crystallographica Section C Structural Chemistry. 2022-11-01, 78 (11): 606–611 [2023-03-28]. ISSN 2053-2296. doi:10.1107/S2053229622009603. （原始内容存档于2023-03-28）.

[Parthe-2] 2.0 ^2.1 E. Parthé, E. Hohnke, F. Hulliger. A new structure type with octahedron pairs for Rh 2 S 3 , Rh 2 Se 3 and Ir 2 S 3. Acta Crystallographica. 1967-11-01, 23 (5): 832–840 [2023-03-28]. ISSN 0365-110X. doi:10.1107/S0365110X67003767. （原始内容存档于2022-12-01）.

[3] Wuxing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Phase Controllable Synthesis of Well-Crystallized Rhodium Sulfides by the Hydrothermal Method. Crystal Growth & Design. 2009-08-05, 9 (8): 3765–3770 [2023-03-28]. ISSN 1528-7483. doi:10.1021/cg900454g. （原始内容存档于2023-03-28）（英语）.

[4] Wu-xing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Solvothermal Preparation and Control of Phase Composition of Nanosized Rhodium Sulfide Particles. Chemistry Letters. 2009-03-05, 38 (3): 210–211 [2023-03-28]. ISSN 0366-7022. doi:10.1246/cl.2009.210 （英语）.

[5] Rh2S3 Structure: A2B3_oP20_60_d_cd. Encyclopedia of Crystallographic Prototypes. [2023-03-28]. （原始内容存档于2023-03-28）.

[6] Shrikant Bhat, Leonore Wiehl, Shariq Haseen, Peter Kroll, Konstantin Glazyrin, Philipp Gollé‐Leidreiter, Ute Kolb, Robert Farla, Jo‐Chi Tseng, Emanuel Ionescu, Tomoo Katsura, Ralf Riedel. A Novel High‐Pressure Tin Oxynitride Sn 2 N 2 O. Chemistry – A European Journal. 2020-02-17, 26 (10): 2187–2194 [2023-03-28]. ISSN 0947-6539. PMC 7065226 . PMID 31671223. doi:10.1002/chem.201904529 （英语）.

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